• 专利附录
  • 专利说明
  • 权利要求
  • 类似技术
  • 同族专利
  • 引用文献
  • 法律状态
  • 优先权
    • 专利摘要:
    high strength cold rolled steel sheet and method of production thereof The present invention relates to high strength cold rolled steel sheet which includes by weight% c: 0.10% to 0.40% , mn: 0.5% to 4.0%, si: 0.005% to 2.5%, cr: 0% to 1.0%, and an iron balance and the inevitable impurities, where the amount of p is limited to 0.05% or less, the amount of s is limited to 0.02% or less, the amount of n is limited to 0.006% or less, the microstructure includes 2% to 30% retained austenite per area percentage , martensite is limited to 20% or less by percentage area in the microstructure, the average cementite particle size is 0.01 <109>, and 30% to 100% of cementite has an aspect ratio of 1 to 3.
    公开号:BR112012018552B1
    申请号:R112012018552-7
    申请日:2011-01-26
    公开日:2019-01-22
    发明作者:Kohichi Sano；Chisato Wakabayashi；Hiroyuki Kawata；Riki Okamoto；Naoki Yoshinaga；Kaoru Kawasaki；Natsuko Sugiura；Nobuhiro Fujita
    申请人:Nippon Steel & Sumitomo Metal Corporation；
    IPC主号:
    专利说明:

    Descriptive Report of the Invention Patent for HIGH RESISTANCE COLD LAMINATED STEEL SHEET AND PRODUCTION METHOD OF THE SAME.
    Field of the Invention
    The present invention relates to a high-strength cold-rolled steel sheet and a method for producing it.
    Priority is claimed over Japanese Patent Application No. 2010-14363, filed on January 20, 2010, Japanese Patent Application No. 2010-88737, filed on April 7, 2010, and Japanese Patent Application No. 2010- 135351, deposited on June 14, 2010, the contents of which are incorporated herein by reference.
    Description of the Relative Technique
    In order to achieve weight reduction and safety, a steel sheet used for car body structures needs to have favorable forming and resistance capabilities. However, generally, when the strength of a steel plate increases, the elongation and expansion of the hole degrade, and the forming capacity of a high-strength steel plate (high-tensile steel plate) deteriorates.
    To resolve such conformability problems, Patent Citations 1 and 2 describe steel sheets that have a retained austenite left in the steel sheet (TRIP steel sheet). In these steel sheets, since transformation-induced plasticity (the TRIP effect) is used, an extremely large elongation can be achieved despite high strength.
    In the steel sheets described in Patent Citations 1 and 2, the amount of C and the amount of Si increases so that the strength of the steel sheet increases and the C is concentrated in austenite. The concentration of C in the austenite stabilizes the retained austenite so that austenite (retained austenite) remains stable at room temperature.
    In addition, as a technique that uses the TRIP effect more effectively, Patent Citation 3 describes a technique in which a hydrodeformation is performed in a temperature range over which
    2/57 the percentage of austenite retained becomes 60% to 90% at the point of maximum stress. In this technique, the expansion ratio of the tube is improved by 150% compared to the same at room temperature. In addition, to improve the deep embossing capacity of the TRIP plate, the citation of 5 Patent 4 describes a forming technique that heats a mold.
    However, in the technique described in Patent Citation 3, the application of the technique is limited to tubes. In addition, in the technique described in Patent Citation 4, heating a mold to obtain a sufficient effect has a high cost, and therefore the application of the technique is restricted,
    Therefore, to effectively develop the TRIP effect instead of improving forming techniques, an additional C addition to the steel plate is considered. The C added to the steel plate concentrates on austenite, but at the same time, crude carbides precipitate. In such a case, the amount of austenite retained in the steel plate decreases, the elongation deteriorates, and fractures due to carbides occur during the bore expansion.
    In addition, when the amount of C is also increased to compensate for the increase in the amount of austenite retained by carbide precipitation, the welding capacity degrades,
    In a steel plate that is used for car body structures, it is necessary to ensure the balance between strength and forming capacity (elongation and expansion of the hole) while increasing the strength. However, as described above, it was difficult to guarantee sufficient forming capacity just by adding C to the steel.
    Here, retained austenite steel (TRIP steel plate) is a high-strength steel plate in which austenite is left in the microstructure of the steel plate that must be formed by controlling the transformation of ferrite and the transformation of bainite during the annealing in order to increase the concentration of C in austenite. Due to the TRIP effect of the retained austenite, the retained austenite steel has a long elongation.
    The TRIP effect has a temperature dependence, and so the TRIP effect can be used to its maximum extent by the formation of
    3/57
    - a steel plate at a high temperature of more than 250 ° C in the case of TRIP steel of conventional techniques. However, if the forming temperature exceeds 250 ° C, problems are likely to occur in relation to the costs of heating a mold. Therefore, it is desirable to 5 It is possible to use the TRIP effect to its maximum extent at room temperature and in a temperature range of 100 ° C to 25 ° C.Patent Citations[Patent Citation 1] Unexamined Japanese Patent Application, First Publication No. S61-217529 10 [Patent Citation 2 Unexamined Japanese Patent Application, First Publication No. H05-59429[Patent Citation 3] Japanese Patent Application Not Examined, First Publication No. 2004-330230 4 [Patent Citation 4] Japanese Patent Application Not Examined 15 , First Publication n ° 2007-111765SUMMARY OF THE INVENTIONProblems to be solved by the inventionAn objective of the present invention is to provide a steel plate that can suppress the fracture during the expansion of the hole and is excellent in 20 balance between resistance and conformability.Methods to solve the problemThe inventors were successful in producing a steel plate that is excellent in terms of strength, ductility (elongation), and expansion of the bore by optimizing the chemical compositions in steel and con- 25 production conditions and controlling the size and shape of the carbides during annealing. The objective is as follows:(1) A high-strength cold-rolled steel sheet according to one aspect of the present invention includes, in mass%, C: 0.10% to 0.40%, Mn: 0.5% to 4.0%, Si: 0.005% to 2.5%, Al: 0.005% to 2.5%, Cr: 0% to 30 1.0%, and a balance of iron and the inevitable impurities, in which the amount of P is limited to 0.05% or less, the amount of S is limited to 0.02% or less, the amount of N is limited to 0.006% or less, and the microstructure
    4/57 includes 2% to 30% of austenite retained by percentage of area and martensite is limited to 20% or less by percentage of area in the microstructure, the average cementite particle size is 0.01 pm to 1 pm, and 30% to 100% of cementite has an aspect ratio of 1 to 3.
    (2) The high-strength cold-rolled steel sheet according to item (1) above may also include, in mass%, one or more types of elements between Mo: 0.01% to 0.3%, Ni: 0.01% to 5%, Cu: 0.01% to 5%, B: 0.0003% to 0.003%, Nb: 0.01% to 0.1%, Ti: 0.01% to 0.2 %, V: 0.01% to 1.0%, W: 0.01% to 1.0%, Ca: 0.0001% to 0.05%, Mg: 0.0001% to 0.05%, Zr: 0.0001% to 0.05%, and REM: 0.0001% to 0.05%.
    (3) In high-strength cold-rolled steel plate as per item (1) or (2) above, the total amount of Si and Al can be 0.5% to 2.5%.
    (4) In high-strength cold-rolled steel plate as per item (1) or (2) above, the average grain size of the retained austenite can be 5 pm or less.
    (5) In the high-strength cold-rolled steel plate according to items (1) or (2) above, the microstructure can include, in percentage area, 10% to 70% ferrite.
    (6) In the high-strength cold-rolled steel plate as per item (1) or (2) above, the microstructure can include, in percentage area, 10% to 70% of ferrite and bainite in total.
    (7) In the high-strength cold-rolled steel plate as per item (1) or (2) above, the microstructure may include, in percentage area, 10% to 75% of bainite and tempered martensite in total.
    (8) On high-strength cold-rolled steel plate as per item (1) or (2) above, the average grain size of the ferrite can be 10 pm or less.
    (9) In cold rolled steel sheet as per item (1) or (2) above, cementite having an aspect ratio of 1 to 3 can be included in 0.003 particles / pm 2 to 0.12 particles / pm 2 .
    (10) In cold-rolled steel sheet of high resistance according to
    5/57 m and item (1) ου (2) above, in the central portion of the plate thickness, the random intensity ratio X of an orientation {100} <001> of the retained austenite and the average value Y of the intensity ratio of a guidance group {110} <111> to {110} <001> of the retained austenite can satisfy the following equation (1):
    4 <2X + Y <10 - (1).
    (11) In the high-strength cold-rolled steel plate according to item (1) or (2) above, in the central portion of the plate thickness, the reason for the random intensity ratio of an orientation {110} <111> of retained austenite for the {110} <001> random orientation intensity of the retained austenite can be 3.0 or less.
    (12) In high-strength cold-rolled steel plate as per item (1) or (2) above, a zinc coating can also be provided on at least one surface.
    (13) On high-strength cold-rolled steel plate as per item (1) or (2) above, a galvannealed coating can also be provided on at least one surface.
    (14) A method of producing a high-strength cold-rolled steel sheet according to one aspect of the present invention includes a first process in which a sheet having the chemical composition according to item (1) or (2) above is laminated hot at a finishing temperature of 820 ° C or higher to produce a hot rolled steel sheet; a second process in which, after the first process, the hot-rolled steel sheet is cooled and wound at a temperature of 25 ° C winding from 350 ° C to 600 ° C; a third process in which the hot rolled steel sheet that underwent the second process is cold rolled to a thickness reduction of 30% to 85% in order to produce a cold rolled steel sheet; a fourth process in which, after the third process, the cold-rolled steel sheet is heated and annealed to an average heating temperature of 750 ° C to 900 ° C; a fifth process, in which the cold rolled steel sheet that underwent the fourth process is cooled at an average cooling rate of 3 ° C / s to 200 ° C / s and kept to a range
    6/57 temperatures from 300 ° C to 500 ° C for 15 seconds to 1200 seconds; and a sixth process in which the cold rolled steel sheet that underwent the fifth process is cooled, in which, in the second process, the first average cooling rate CR1 ° C / s from 750 ° C to 650 ° C is 15 ° C / s to 100 ° C / s, the second average cooling rate CR2 ° C / s from 650 ° C to winding temperature CT ° C is 50 ° C / s or less, the third average cooling rate CR3 ° C / s since after winding up to 150 ° C is 1 ° C / s or less, the winding temperature CT ° C and the first average cooling rate CR1 ° C / s satify, equation (2) below and, in fourth process, in a case in which the amounts of Si, Al, r Cr are represented by [Si], [Al], and [Cr] in terms of mass%, respectively, the average area S pm 2 of perlite included in the hot rolled steel plate that underwent the second process, the average heating temperature T ° C, and the heating time ts satisfy the relationship of equation (3) below.
    1500 <CR1 x (650 -CT) <15000 ··· (2)
    2200> T x log (t) / (1 + 0.3 [Si] + 0.5 [AI] + [Cr] + 0.5S)> 110 (3) (15) In the steel sheet production method high-strength cold-rolled as per item (14) above, the total reduction in thickness of the last two steps in the first process can be 15% or more.
    (16) In the production method of the high-strength cold-rolled steel sheet as per item (14) above, the cold-rolled steel sheet that underwent the fifth process and must undergo the sixth process can be coated with zinc.
    (17) In the production method of high-strength cold-rolled steel sheet as per item (14) above, the cold-rolled steel sheet that underwent the fifth process and must undergo the sixth process can be galvanized and annealed in 400 ° C to 600 ° C for connection.
    (18) In the production method of high-strength cold-rolled steel plate as per item (14) above, the average heating rate of 600 ° C to 800 ° C in the fourth process can be Ο, ΓΟ / s to 7 ° C / s.
    (19) In the production method of the high-strength cold-rolled steel sheet according to item (14) above, before the first process, the
    7/57 plate can be cooled to 1000 ° C or lower and reheated to 1000 ° C or higher.
    Effects of the Invention
    According to the present invention, it is possible to provide a high-strength steel sheet that is excellent in terms of strength and forming capacity (elongation and hole expansion at room temperature and in a warm range) by optimizing the chemical composition, ensuring a predetermined amount of austenite retained, and to properly control the size and shape of the cementite.
    In addition, according to the present invention, it is possible to produce a high-strength steel sheet that is excellent in terms of strength and forming capacity by properly controlling the cooling rate of the steel sheet after hot rolling (before and after cooling) and the cooling conditions after cold rolling.
    In addition, in the high-strength cold-rolled steel plate as per item (4) above, the elongation can also be improved in a warm band.
    In addition, in the high-strength cold-rolled steel plate as per item (10) above, it is possible to guarantee a great uniform elongation in any directions while the anisotropy in the plane is rarely presented.
    BRIEF DESCRIPTION OF THE DRAWINGS
    Figure 1 is a graph showing the relationship between the annealing parameter P and the average cementite particle size.
    Figure 2 is a graph showing the relationship between the average size and grain of cementite and the balance between strength and conformation capacity product of the tensile strength TS, uniform elongation uEL, and bore expansion (λ).
    Figure 3 is a graph showing the relationship between the average cementite grain size and the balance between strength and forming capacity (product of TS tensile strength and bore expansion λ).
    8/57
    Figure 4 is a view showing the main orientation of the austenite phases in the ODF in a cross section for which Φ2 is 45 °.
    Figure 5 is a view showing the relationship between a 2X + Y parameter and the AuEL anisotropy index of uniform elongation.
    Figure 6 is a view showing the flow chart of a method of producing a high-strength cold-rolled steel sheet according to one embodiment of the present invention.
    Figure 7 is a view showing the relationship between the winding temperature CT and the first average cooling rate CR1 in the method of producing high-strength cold-rolled steel sheets according to the modality.
    Figure 8 is a view showing the relationship between the tensile strength TS and the elongation tEL 15 o at 150 ° C in the Examples and in the Comparative Examples.
    DETAILED DESCRIPTION OF THE INVENTION
    The inventors found that the balance between strength and conformability (ductility and bore expansion) becomes excellent when the cementite formed during hot rolling is melted during heating for annealing in order to decrease the particle size of the cementite in one steel sheet. Hereafter, the reasons will be described.
    In TRIP steel, C is concentrated in austenite in order to increase the amount of austenite retained in an annealing process. An increase in the amount of C in austenite and an increase in the amount of austenite improves the tensile properties of TRIP steel. However, in a case where the cementite formed during hot rolling remains after annealing (annealing after cold rolling), part of the C added to the steel is present in the form of carbides. In this case, there are cases in which the amount of austenite and the amount of C in the austenite decrease, and the balance between resistance and ductility deteriorates. In addition, carbides act as a starting point for fractures during hole expansion tests, and the forming ability deteriorates. In addition,
    9/57 carbides act as fracture starting points during hole expansion tests, and the forming ability deteriorates.
    The reasons are not clear, but are considered to be as follows. When the particle size of cementite decreases to a critical size or less, deterioration of the local elongation that originates from cementite is prevented, and the solute C that is obtained by dissolving cementite can be concentrated in austenite. In addition, in this case, the area ratio of retained austenite and the amount of C in the retained austenite increases, and the stability of the retained austenite increases. As a result, the TRIP effect improves due to the synergy effect of preventing the deterioration of local elongation that originates from cementite and the improvement in stability of retained austenite.
    To effectively show the synergy effect, the average particle size of cementite needs to be 0.01 μητ to 1 μπι after annealing. In order to more reliably prevent deterioration of local elongation and also increase the amount of C supplied to austenite retained from cementite, the average particle size (average particle diameter) of cementite is preferably 0.9 pm or less, more preferably 0 , 8 μιτι or less, and more preferably 0.7 pm or less. When the average particle size of cementite exceeds 1 μηη, since the C does not concentrate sufficiently, the TRIP effect is not optimal in a temperature range of 100C to 250C as well as at room temperature, local elongation deteriorates due to crude cementite , and the stretching deteriorates abruptly due to synergistic action. On the other hand, although the average particle size of cementite is desirably as small as possible, the average particle size must be 0.01 μιτι or more to suppress the growth of the ferrite grain. In addition, as described below, the average particle size of cementite is dependent on the heating temperature and the heating time during annealing. Therefore, from an industrial point of view as well as from the point of view of microstructure control, the average particle size of cementite is preferably 0.02 μιτι or more, more preferably 0.03 pm or more, and more preferably
    10/57
    0.04 gin or more.
    Meanwhile, the average particle size of cementite is obtained by averaging the equivalent circle diameters of cementite particles when cementite in the microstructure of the steel sheet is observed using an optical microscope, an electron microscope, or similar .
    The inventors investigated a method for decreasing the average particle size of cementite. The inventors studied the relationship between the average area of perlite in a hot-rolled steel sheet and the amount of cementite dissolved depending on the heating temperature and the heating time during annealing.
    As a result, it was found that when the average area S (μίτι 2 ) perlites the microstructure of the steel sheet after hot rolling, the average heating temperature T (° C) during annealing, and the heating time t (s) during annealing satisfies equation (4) below, the average particle size of cementite after annealing becomes 0.01 μΐη to 1 μηχ and the concentration of C in the retained austenite phases is accelerated as shown in figure 1 Meanwhile, in figure 1, to eliminate the influence of the amount of carbon, steel having a C content of approximately 0.25% is used, and cementite is observed using an optical microscope.
    2200> T x (og (t) / (1 + 0.3 [Si] + 0.5 [AI] + [Cr] + 0.5S)> 110 - (4)
    Here, [Si], [Al], and [Cr] represent the amounts (% by mass) of Si, Al, and Cr on a steel plate, respectively. In addition, log in equation (4) indicates a common logarithm (with base 10).
    Here, to simplify the description below, annealing parameters P and a are introduced, which are represented in equations (5) and (6) below.
    P = T χ log (t) / a - (5) α = (1 + 0.3 [Si] + 0.5 [AI] + [Cr] + 0.5S) - (6)
    The lower limit of the annealing parameter P is necessary to decrease the average particle size of cementite. To decrease the ta
    11/57 cementite particle run to 1 pm or less, it is necessary to anneal under conditions of an annealing parameter P of more than 110. In addition, the upper limit of the annealing parameter P is necessary to reduce the necessary costs for annealing and to guarantee the cementite that fixes the ferrite grain. To ensure cementite having an average particle size of 0.01 pm or more that can be used for fixation, it is necessary to perform annealing under conditions of an annealing parameter P of less than 2200. As such, the annealing parameter P needs be greater than 110 and less than 2200.
    Meanwhile, to also decrease the average particular size of the cementite as described above, the annealing parameter P is preferably more than 130, more preferably more than 140, and more preferably more than 150. In addition, to sufficiently guarantee the average size of cementite particle which can be used to set, as described above, the annealing parameter P is preferably less than 2100, more preferably less than 2000, and more preferably still less than 1900.
    When equation (4) above is satisfied, the cementite in the perlite formed during the winding of the steel sheet after hot rolling is spheroidized during heating for annealing and a large spherical cementite is formed in the middle of the annealing. Spherical cementite can be dissolved at an annealing temperature of point A c1 or higher, and when equation (4) is satisfied, the average particle size of cementite decreases sufficiently to be 0.01 pm to 1 pm.
    Here the physical meaning of the annealing parameter terms (equation (5)) will be described.
    T x log (t) in the annealing parameter P is considered to be associated with the diffusion rates (or diffusion amounts) of carbon and iron. This is because the transformation from cementite to aistenite proceeds as the atoms spread.
    a in the annealing parameter P increases in a case where the amounts of Si, Al and Cr are large, or the average area S of the perlite that
    12/57 is formed during the winding of the hot-rolled steel sheet is large. To satisfy equation (4) in a case where α is large, it is necessary to change the annealing conditions so that T χ log (t) increases.
    The reasons why α (equation (6)) in equation (5) changes by the amount of Si, Al and Cr and the perlite area ratio after the hot rolled steel sheet is wound are as follows:
    Si and Al are elements that suppress cementite precipitation. Therefore, when the amounts of Si and Al increase, the transformation from austenite to ferrite and bainite having a small amount of carbonates becomes liable to proceed during the winding of the steel sheet after hot rolling, and the carbon is concentrated in the austenite. After that, the austenite is transformed, in which the carbon is concentrated in the perlite. In such a perlite having a high carbon concentration, since the cementite fraction is large, and cementite in the perlite is capable of spheroidizing and hard to be dissolved during the subsequent heating for annealing, the crude cementite is liable to be formed. As such, the terms including [Si] and [Al] in α are considered to correspond to a decrease in the rate of cementite solution due to the formation of crude cementite and an increase in the solution time.
    Cr is an element that forms a solid solution in cementite in order to make it difficult to dissolve cementite (in order to stabilize cementite). Therefore, when the amount of Cr increases, the value of ct in equation (5) increases. As such, the terms including [Cr] in α are considered to correspond to the decrease in the rate of cementite solution due to the stabilization of cementite.
    It is considered that when the average area S of perlite is relatively large after winding the hot rolled steel sheet, the atom diffusion distance required for the reverse transformation becomes large, and therefore the average particle size of the Annealed cementite is likely to become large. Therefore, when the average area S of perlite increases, α in equation (5) increases. As such, the term including the
    13/57 mean area S of perlite in α is considered to correspond to an increase in the cementite solution time due to an increase in the atom diffusion distance.
    For example, the average area S of perlite is obtained by measuring the area of a statistically sufficient number of perlite grains through an image analysis of an optical microphotograph of a cross section of the hot-rolled steel sheet, and calculating it if the average of your areas.
    As such, α is a parameter that indicates how easily cementite remains after annealing, and it is necessary to determine the annealing conditions according to ο α in order to satisfy equation (4) above.
    As such, when annealing is carried out under annealing conditions that satisfy equation (4), the average particle size of cementite decreases sufficiently, cementite is suppressed from acting as a starting point for breakages during expansion of the hole, and total amount of C that is concentrated in austenite that is concentrated in austenite increases. Therefore, the amount of austenite retained in the microstructure increases, and the balance between resistance and ductility improves. For example, the balance between strength and conformability improves in a case where the average particle size of cementite present in steel is 1 pm or less as shown in FIGS. 2 and 3. Meanwhile, in figure 2, the balance between strength and forming capacity of the steel sheet shown in figure 1 is assessed using the product of TS tensile strength, uniform elongation uEL, and bore expansion λ. In addition, in figure 3, the balance between strength and forming capacity of the steel sheet shown in figure 1 is assessed using the product of the tensile strength TS and the expansion of the λ hole.
    In addition, as a result of in-depth studies, the inventors found that, in a case where it is necessary to decrease the anisotropy in the plane during forming, it is extremely important to control the orientation of the crystal (texture) of the austenite phases. To control the texture of the
    14/57 austenite phases, it is extremely important to control the texture of the ferrite formed during annealing. Since the retained austenite phases that remain in a plate product are formed due to the inverse transformation of the ferrite phase interfaces during annealing, the retained austenite phases are significantly influenced by the crystal orientation of the ferrite phases.
    Therefore, in order to decrease anisotropy in the plane, it is important to control the ferrite texture to be transformed into austenite and to have austenite inherit the crystal orientation during the subsequent reverse transformation. That is, to optimize the ferrite texture, the coiling temperature during hot rolling is controlled, the hot rolled sheet is prevented from having a single phase bainite microstructure, and the hot rolled sheet is cold rolled to a adequate thickness reduction. A desired crystal orientation can be produced through such a control. In addition, to make the austenite phases inherit the texture of the ferrite phases, it is important to sufficiently recrystallize the cold-rolled microstructure during annealing, to increase the temperature of a double phase region, and to optimize the austenite fraction in the double phase region. Therefore, to increase as much as possible the stability of the retained austenite, in a case where it is necessary to decrease the anisotropy in the plane during forming, it is desirable to adequately control the above conditions.
    Hereinafter, the high-strength cold-rolled steel sheet (for example, having a tensile strength of 500 MPa to 1800 MPa) will be described in detail according to one embodiment of the present invention.
    Initially, the basic components of the steel sheet of the modality will be described. Meanwhile, hereinafter, "%" which indicates the quantities of chemical elements refers to% by mass.
    C: 0.10% to 0.40%
    C is an extremely important element to increase the strength of the steel and guarantee the retained austenite. In order to guarantee a sufficient amount of austenite retained, an amount of C of 0.10% or more is required. On the other hand, when C is excessively included in steel, the
    15/57 welding capacity is impaired, and thus the upper limit on the amount of C is 0.40%. In addition, to ensure more retained austenite and increase the stability of retained austenite, the amount of C is preferably 0.12% or more, more preferably 0.14% or more, and most preferably still 0.16% or more. To also guarantee the weldability, the amount of C is preferably 0.36% or less, more preferably 0.33% or less, and more preferably, 32% or less.
    Mn: 0.5% to 4.0%
    Mn is an element that stabilizes austenite and increases the hardening capacity. To ensure sufficient curing capacity, an amount of Mn of 0.5% or more is required. On the other hand, when Mn is excessively added to steel, ductility is impaired and, therefore, the upper limit of the amount of Mn is 4.0%. The preferred upper limit for the amount of Mn is 2.0%. To also increase the stability of austenite, the amount of Mn is preferably 1.0% or more, more preferably 1.3% or more, and most preferably still 1.5% or more. In addition, to ensure a more favorable forming capacity, the amount of Mn is preferably 3.0% or less, more preferably 2.6% or less, and more preferably still 2.2% or less.
    Si: 0.005% to 2.5%
    Al: 0.005% to 2.5%
    Si and Al are deoxidizing agents, and steel must each include Si and Al by 0.005% or more to perform sufficient deoxidation. In addition, Si and Al stabilize ferrite during annealing and suppress cementite precipitation during the transformation of bainite in order to increase the concentration of C in austenite and contribute to guarantee retained austenite. More retained austenite can be guaranteed, as the amounts of Si and Al increase, and therefore the amount of Si and the amount of Al are each preferably 0.30% or more, more preferably 0.50% or more, and most preferably 0.80% or more. When Si or Al is added excessively to the steel, the surface properties (for example, galvannealing or
    16/57 of chemical conversion), the coating capacity and the welding capacity deteriorate, and therefore the upper limits for the amount of Si and the amount of Al are each adjusted by 2.5%. In a case where the surface properties, coating capacity, and weldability are required when the steel sheet is used as a part, the upper limits of each between the amount of Si and the amount of Al are preferably 2 , 0%, more preferably 1.8%, and most preferably 1.6%.
    Meanwhile, in a case where a large amount of both Si and Al is added to the steel, it is desirable to evaluate the sum (Si + Al) of the Si amount and the Al amount. That is, Si + Al is preferably 0.5% or more, more preferably 0.8% or more, even more preferably 0.9% or more, and most preferably still 1.0% or more. In addition, Si + Al is preferably 2.5% or less, more preferably 2.3% or less, even more preferably 2.1% or less, and more preferably still 2.0% or less.
    Cr: 0% to 1.0%
    Cr is an element that increases the strength of the steel plate. Therefore, in a case where Cr is added in order to increase the strength of the steel plate, the amount of Cr is preferably 0.01% or more. However, when 1% or more of Cr is included in the steel, since sufficient ductility cannot be guaranteed, the amount of Cr must be 1% or less. In addition, since Cr forms solid solutions in the cementite in order to stabilize the cementite, the cementite solutions are suppressed (delayed) during annealing. Therefore, the amount of Cr is preferably 0.6% or less, and more preferably 0.3% or less.
    In the following, among the unavoidable impurities, will be described impurities that need to be particularly reduced. Meanwhile, the lower limits of these impurities (P, S and N) can be 0%,
    P: 0.05% or less
    P is an impurity and impairs ductility and the ability to
    17/57 welding when excessively included in steel. Therefore, the upper limit for the amount of P is 0.05%. In a case where more forming capacity is required, the amount of P is preferably 0.03% or less, more preferably 0.02% or less, and more preferably 0.01% or less.
    S: 0.020% or less
    S is an impurity and, when included excessively in steel, it forms elongated MnS due to hot rolling and deteriorates the forming capacity, such as ductility, hole expansion, etc. Therefore, the upper limit of the amount of S is preferably 0.010% or less, more preferably 0.008% or less, and more preferably 0.002% or less.
    N is an impurity and, when the amount of N exceeds 0.006%, ductility deteriorates. Therefore, the upper limit for the amount of N is 0.006%. In a case where more forming capacity is required, the amount of N is preferably 0.004% or less, more preferably 0.003% or less, and more preferably 0.002% or less.
    Optional elements will now be described.
    In addition, in addition to the above basic components, one or more types of elements between Mo, Ni, Cu, and B can be added to the steel as needed. Mo, Ni, Cu, and B are elements that improve the strength of the steel plate. To obtain the effect, the amount of each element between Mo, the amount of Ni, and the amount of Cu is preferably 0.01% or more, and the amount of B is preferably 0.0003% or more. In addition, in a case where it is also necessary to guarantee resistance, the lower limits of the amount of Mo, the amount of Ni and the amount of Cu are more preferably 0.03%, 0.05% and 0.05%, respectively . Similarly, the amount of B is preferably 0.0004% or more, more preferably 0.0005% or more, and most preferably 0.0006% or more. On the other hand, when these chemical elements are added to steel excessively, the resistance increases excessively and there are cases in which the ductility is degraded. Particularly, when B
    18/57 is excessively added to the steel in order to increase the hardening capacity, the transformation of ferrite and the transformation of bainite start late, and the concentration rate of C the austenite phases decreases. In addition, in a case where Mo is excessively added to steel, there are cases where the texture degrades. Therefore, in a case where ductility needs to be guaranteed, it is desirable to control the amount of Mo, the amount of Ni, the amount of Cu, and the amount of B. Therefore, the upper limit of the amount of Mo is preferably 0, 3%, and more preferably 0.25%. In addition, the upper limit of the amount of Ni is preferably 5%, more preferably 2%, even more preferably 1%, and most preferably 0.3%. The upper limit for the amount of Cu is preferably 5%, more preferably 2%, even more preferably 1%, and most preferably 0.3%. The upper limit of the amount of B is preferably 0.003%, more preferably 0.002%, even more preferably 0.0015%, and most preferably 0.0010%.
    Also, in addition to the basic components above, one or more types of elements between Nb, Ti, V, and W can be added as needed to the steel. Nb, Ti, V, and W are elements that form fine carbides, nitrides or carbonitrides, and improve the strength of the steel plate. Therefore, to also ensure resistance, the amount of each between the amount of Nb, the amount of Ti, the amount of V, and the amount of W is preferably 0.01% or more, and more preferably 0.03% or more. On the other hand, when these elements are added excessively to the steel, the resistance increases excessively so that the ductility degrades. Therefore, the upper limit of the amount of Nb, the amount of Ti, the amount of V and the amount of W are preferably 0.1%, 0.2%, 1.0% and 1.0% respectively, and more preferably 0.08%, 0.17%, 0.17% and 0.17%, respectively.
    In addition, in addition to the above basic components, 0.0001% to 0.05% of one or more types of elements between Ca, Mg, Zr, and rare earth metals (REM) are preferably included in the steel. Ca, Mg, Zr, and REM have an effect of controlling the forms of sulfides and oxides in order to
    19/57 improve local ductility and borehole expansion. To obtain the effect, the amount of Ca, the amount of MG, the amount of Zr, and the amount of REM are each preferably 0.0001% or more, and more preferably 0.0005% or more. On the other hand, when these elements are excessively added to steel, the forming capacity deteriorates. Therefore, the amount of Ca, the amount of Mg, the amount of Zr and the amount of REM are preferably each 0.05% or less, and more preferably 0.05 or less, and more preferably 0.04% or less. In addition, in a case where several types of these elements are added to the steel, the total amount of the elements is more preferably 0.0005% to 0.05%.
    Next, the microstructure (structure) of the high-strength cold-rolled steel sheet of the modality will be described. The microstructure of the high-strength cold-rolled steel sheet of the modality must include retained austenite. In addition, most of the remaining microstructure can be classified into ferrite, bainite, martensite, and tempered martensite. Henceforth, “%” which indicates the quantity of each phase (microstructure) refers to a percentage of area (area ratio). Meanwhile, since carbides, more like cementite, are not evaluated in the microstructure area ratio.
    Retained austenite increases ductility, particularly uniform elongation through Ada transformation-induced plasticity. Therefore, the microstructure needs to include 2% or more of austenite retained in terms of area ratio. In addition, since the retained austenite is transformed into martensite through conformation, the retained austenite also contributes to improving the strength. Particularly, in a case where a relatively large amount of an element such as C is added to the steel to guarantee the retained austenite, the area ratio of the retained austenite is preferably 4% or more, more preferably 6% or more, and even more preferably 8% or more.
    On the other hand, a larger area ratio of retained austenite is more preferable. However, to guarantee 30% retained austenite hands
    20/57 in terms of area ratio, it is necessary to increase the amounts of C and Si, and the weldability or surface properties are degraded. Therefore, the upper limit of the retained austenite area ratio is 30%. In a case where the weldability and surface properties also need to be guaranteed, the upper limit of the retained austenite area ratio is preferably 20%, more preferably 17%, and most preferably 15%.
    In addition, the size of the retained austenite strongly influences the stability of the retained austenite. As a result of repeated studies regarding the stability of retained austenite in a temperature range of 100 ° C to 250 ° C, the inventors found that when the average grain size of the retained austenite is 5 pm or less, the retained austenite is evenly dispersed in the steel, and the TRIP effect of the retained austenite can be presented more effectively. That is, when the average grain size of the retained austenite is adjusted to 5 pm or less, the elongation over a temperature range of 100 ° C to 250 ° C can be drastically improved even in a case where the elongation is low at room temperature. Therefore, the average grain size (average grain diameter) of the retained austenite is preferably 5 pm or less, more preferably 4 pm or less, even more preferably 3.5 pm or less, and most preferably still 2.5 pm or less .
    As such, the average grain size of the retained austenite is preferably small, but the average grain size depends on the heating temperature and the heating time during annealing, and so is preferably 1.0 pm or more from a point of view. industrial.
    Since martensite is hard, resistance can be guaranteed. However, if the martensite area ratio exceeds 20%, ductility is insufficient, and therefore it is necessary to control the martensite area ratio to be 20% or any less. In addition, to also ensure the forming ability, the area ratio of martensite is preferably controlled to be 15% or less, more preferably 10% or less, and more preferably still 7% or less. On the other hand, when martensite is reduced
    As the resistance degrades, the area ratio of martensite is preferably 3% or more, more preferably 4% or more, and more preferably 5% or more.
    The microstructure remaining in the microstructure above includes at least one between ferrite, bainite and tempered martensite. Its area ratio is not particularly limited, but it is desirably in the following area ratio range in consideration of the balance between elongation and strength:
    Ferrite is a microstructure that is excellent in terms of ductility, but excess ferrite reduces strength. Therefore, to obtain an excellent balance between strength and ductility, the ferrite area ratio is preferably 10% to 70%. The ferrite area ratio is controlled according to the desired resistance level. In a case where ductility is required, the area ratio of ferrite is more preferably 15% or more, even more preferably 20% or more, and most preferably still 30% or more. In addition, in a case where strength is required, the ferrite area ratio is more preferably 65% or less, even more preferably 60% or less, and most preferably still 50% or less.
    The average ferrite grain size is preferably 10 pm or less. As such, when the average diameter of the ferrite grain is 10 pm or less. The strength of the steel sheet can increase without degrading the total elongation or uniform elongation. This is considered to be because when the ferrite grains are made to be fine, the microstructure becomes uniform, and therefore the stresses introduced during forming are uniformly dispersed, and the stress concentration decreases so that it becomes difficult for the steel plate. be fractured. In addition, in a case where strength needs to be increased while elongation is maintained, the average ferrite grain size is more preferably 8 pm or less, even more preferably 6 pm or less, and most preferably still 5 pm or less . The lower limit of the average ferrite grain size is not particularly limited. However, the average ferrite grain size is not particularly limited. However, the average ferri grain size
    22/57 ta is preferably 1 μιτι or more, more preferably 1.5 μηη or more, and most preferably 2 pm or more from an industrial point of view in consideration of the tempering conditions.
    In addition, ferrite and bainite are necessary to concentrate C in the retained austenite and improve ductility through the TRIP effect. To obtain excellent ductility, the total ferrite and bainite area ratios are preferably 10% to 70%. When the total area ratios of ferrite and bainite are changed in a range of 10% to 70%, it is possible to maintain a favorable elongation at room temperature and in a warm range and to obtain a desired strength reliably. To concentrate more C in the retained austenite, the total amount of ferrite and bainite area ratios is more preferably 15% or more, even more preferably 20% or more, and most preferably still 30% or more. In addition, to sufficiently guarantee the amount of austenite retained in the final microstructure, the total amount of ferrite and bainite area ratios is more preferably 65% or less, even more preferably 60% or less, and more preferably 50% or less.
    In addition, bainite (or bainitic ferrite) and tempered martensite can be the remainder (balance) of the final microstructure. Therefore, the total area ratio of bainite and tempered martensite is preferably 10% to 75%. Therefore, in a case where resistance is required, the total area ratio of bainite and tempered martensite is preferably 15% or more, even more preferably 20% or more, and most preferably still 30% or less. In addition, in a case where ductility is required, the total area ratio of bainite and tempered martensite is more preferably 65% or less, even more preferably 60% or less, and more preferably still 50% or less. Among them, since bainite is a microstructure necessary to concentrate C in the retained austenite, (γ), the microstructure preferably includes 10% or more of bainite. However, when the microstructure includes a large amount of bainite, the amount of ferrite having favorable hardening characteristics decreases, and uniform elongation decreases, and therefore the bainite area ratio is preferably
    23/57
    75% or less. Particularly, in a case where it is necessary to guarantee the amount of ferrite, the banita area ratio is more preferably 35% or less.
    In addition, in a case where more ductility is guaranteed by tempering the martensite that is formed in a production process, the area ratio of tempered martensite in the microstructure is preferably 35% or less, and more preferably 20% or less. Meanwhile, the lower limit of the tempered martensite area ratio is 0%.
    So far, the microstructure of the high-strength cold-rolled steel sheet of the modality has been described, but there are cases where, for example, 0% to 5% perlite remains in the microstructure when the cementite in the microstructure that will be described below is controlled properly.
    In addition, cementite will be described in the microstructure of the steel sheet of the modality.
    To improve the TRIP effect and suppress ferrite grain growth, the average size of cementite particle needs to be 0.01 pm to 1 pm. As described above, the upper limit of the average cementite particle size is preferably 0.9 pm, more preferably 0.8 pm, and most preferably 0.7 pm. In addition. The lower limit of the average size of the cementite particle is preferably 0.02 pm, more preferably 0.03 pm, and most preferably 0.04 pm.
    Meanwhile, in order to sufficiently concentrate C in austenite and prevent the cementite above from acting as a starting point for fractures during the expansion of the hole, it is necessary to sufficiently spheroidize the cementite in the perlite. Therefore, cementite needs to include 30% to 100% cementite having an aspect ratio (the ratio of the length of the long axis to the length of the short axis of the cementite) from 1 to 3. In a case where further expansion of the hole, the number ratio (spheroidization ratio) of cementite particles having an aspect ratio of 1 to 3 for all cementite particles is preferably 36% or more, more preferably 42% or more, and even more preferably 48% or more. In a case where it is necessary to reduce the cost of the necessary annealing
    24/57 for cementite spheroidization or production conditions are limited, the present ratio is preferably 90% or less, more preferably 83% or less, and more preferably 80% or less.
    Since such spheroidal cementite (undissolved spheroidal cementite) remains in austenite during inverted transformation and part of it suppresses the growth of the ferrite grain, the spheroidized cementite is present within the retained austenite grains or at the edges of the ferrite grains.
    Here, for example, there are cases where cementite that does not form directly from perlite (cementite in the form of a film formed at the interfaces of bainitic ferrite or cementite in bainitic ferrite) causes fracture at the grain edges. Therefore, it is desirable to reduce cementite that does not form directly from perlite as much as possible.
    In addition, the amount of spheroidal cementite in the microstructure changes depending on chemical components and production conditions, and thus is not particularly limited. However, to increase the fixation effect that suppresses the growth of ferrite grain, 0.003 or more cementite particles having an aspect ratio of 1 to 3 are preferably included per square micrometer. In a case where the fixing effect needs to be further increased, the number of spheroidal cementite particles included per square micrometer is more preferably 0.005 or more, even more preferably 0.007 or more, and most preferably 0.01 or more. In addition, in a case where it is also necessary to concentrate C in austenite, the number of spheroidal cementite particles included per square micrometer is preferably 0.12 or less, more preferably 0.1 or less, even more preferably 0.08 or less, and most preferably 0.06 or less.
    Furthermore, in a case where a high uniform elongation needs to be guaranteed in all directions on the surface of the plate without causing anisotropy in the plane, it is desirable to control the distribution of the crystal orientation (texture) of the retained austenite. In this case, austenite is stable in relation to deformation in a <100> crystal orientation, and therefore the
    25/57 crystal orientations including <100> are evenly dispersed on the plate surface.
    Regarding the crystal orientations, generally, an orientation perpendicular to the plate surface is represented by (hkl) or {hkl}, and an orientation parallel to the lamination direction is represented by [uvw] or <uvw>. {hkl} and <uvw> are collective terms for equivalent surfaces, and [hkl] and (uvw) indicate individual crystal surfaces. Meanwhile, in the description of the crystal orientations, the previous expressions of {hkl} and <uvw> are used. It is known that, among the crystal orientations that develop in the austenite phases, orientations including a <100> orientation on the plate surface include an {100} <001> orientation for which the plate surface orientation is {100} and an orientation group {110} <111> to {110} <001> (orientation group {110}) for which the plate surface orientation is {110}. In the case of the {100} <001> orientation, the <001> orientation is aligned to a direction parallel to the lamination direction and to a direction parallel to the sheet width direction. Therefore, when austenite retained in the above orientation increases, the stability of austenite in relation to the deformation in the rolling direction and the direction of the sheet width increases, and a uniform elongation in the direction increases. However, since uniform elongation, for example, in a direction rotated by 45 in the direction of the width of the plate (direction 45 °) does not improve, when the above orientation alone develops strongly, anisotropy is shown in uniform elongation. Meanwhile, in the case of the orientation group {110}, an orientation <100> parallel to the surface of the plate is present in relation to each of the orientations included in the orientation group. For example, in the case of the {110} <111> orientation, the <100> orientation faces the 55 ° rotated direction in the direction of the sheet width from the lamination direction (55 ° direction). Therefore, when the austenite retained in the above orientation increases, the uniform elongation in the 55 ° direction increases.
    The above facts show that uniform stretching improves when the ratio of intensity of the orientation or group of orientations
    26/57 above increases. To sufficiently increase uniform elongation, a parameter 2X + Y shown in equation (7) below is preferably greater than 4. When parameter 2X + Y is 4 or less, orientations are often not present as a crystal orientation group , and it is difficult to obtain an effect of stabilizing austenite by controlling the orientations of the crystal. From the point of view above, parameter 2X + Y is preferably 5 or more. Meanwhile, when the texture of the austenite phases develops, and its intensity ratio increases excessively, there is a tendency in which the intensity ratio of an orientation group {110} <111> to {110} <112> between the guidance group {110} <111> to {110} <001> increases. As a result, only uniform stretching in a 45 ° direction improves, and anisotropy is likely to be exhibited. From the above point of view, parameter 2X + Y in equation (7) below is preferably less than 10, and more preferably 9 or less.
    4 <2X + Y <10 - (7)
    On here,
    X refers to an average value of the random intensity ratios of the austenite phases (retained austenite phases) in the {100} <001> orientation in a half-thickness position of a plate (the central portion); and
    Y refers to an average value of the random intensity ratios of the austenite phases (retained austenite phases) in the guidance group {110} <111> to {110} <001> in a half-thickness position of a plate (the portion central).
    In addition, from the point of view of suppressing the anisotropy display, {110} <111> / {110} <001> which is the ratio of the random intensity ratio of the {110} <111> orientation to the random intensity ratio of the {110} <001> orientation is preferably deleted to be 3.0 or less, and preferably 2.8 or less. The lower limit of the {110} <111> / {110} <001> ratio is not particularly limited, and can be 0.1.
    Each average value of the random intensity ratios of the {100} <001> orientation, the {110} <111> orientation, the {110} <001> orientation and the random intensity ratio of the {110} <111> orientation group a {110}
    27/57 <001> can be obtained from the orientation distribution functions (hereinafter referred to as ODF) which indicates the three-dimensional textures. ODF is computed by the series expansion method based on the numbers {200}, {311}, and {220} of the austenite phase measured using X-ray diffraction. Meanwhile, the random intensity ratio refers to a value numerical obtained by measuring the X-ray intensities of a standard specimen that does not accumulate in a specific orientation and a specimen under the same conditions by X-ray diffractometry or similar, and dividing the X-ray intensity obtained from the specimen by the X-ray intensity of the standard specimen.
    Figure 4 shows the ODF of a cross section for which φ 2 έ 45 °. In figure 4, the three-dimensional texture is shown by the Bunge notation using the orientation distribution functions. In addition, the Euler angle φ 2 is set to 45 °, and (hkl) [uvw] which is the specific orientation is expressed using an Euler angle φ ^ Φ of the orientation distribution functions. For example, as shown by points on the axis with Φ = 90 ° in figure 4, the orientation group {110} <111> to {110} <001> is expressed in a range in which φι = 35 ° to 90 °, Φ = 90 °, and φ 2 = 45 ° are satisfied. Thus, the average value of the random intensity ratios of the {110} <111> to {110} <001> orientation group can be obtained by calculating the average of the random intensity ratios in a range in which φι is in a 35 ° to 90 ° range.
    Meanwhile, as described above, the orientation of the crystal is usually expressed using (hkl) or {hkl} for an orientation perpendicular to the plate surface and [uvw] or <uvw> for an orientation parallel to the lamination direction. {hkl} and <uvw> are collective terms for equivalent surfaces, and (hkl) and [uvw] indicate individual crystal surfaces. Here, since the objective is a centered face cubic structure (hereinafter referred to as the fcc structure), for example, the planes (111), (111), (1-11), (11-1), (-1 -11), (-11-1), (1-1-1), and (-1-1-1) are all equivalent, and these plans cannot be differentiated. In such a case, those guidelines are collectively referred to as {111}. Meantime,
    28/57 since ODF is also generally used to express orientations of a crystal structure having a low symmetry, the orientations are expressed in a range of φι from 0 o to 360 °, Φ from 0 o to 180 °, and φ2 from 0 o to 360 °, and individual orientations are expressed by (hkl) [uvw]. However, here, since the objective is a fcc structure having a high symmetry, Φ and φ2 are expressed in a range from 0 o to 90 °. In addition, the range of φι changes depending on whether the symmetry due to the deformation is taken into account or not when the computation is performed, but φι is expressed by 0 o to 90 ° in consideration of the symmetry. That is, a method is selected in which the average value of the same orientation having φ1 from 0 o to 360 ° is expressed in an ODF having φι from 0 o to 90 °. In this case, (hkl) [uvw] and {hkl} <uvw> have the same meaning. Therefore, for example, the random X-ray intensity ratio (random intensity ratio) of (110) [1-11] of an ODF in a cross section having φ2 of 45 °, which is shown in figure 1, is the X-ray intensity ratio of an orientation {110} <111>.
    The specimen for X-ray diffraction is prepared as follows: a steel sheet is polished to a predetermined position in the direction of the sheet thickness using a polishing method, such as mechanical polishing or chemical polishing, the surface of the steel sheet is finished to be a mirrored surface by polishing, then stresses are removed using a polishing method, such as electrolytic polishing or chemical polishing, and at the same time, the half-thick portion (central portion of the plate thickness) is adjusted to be the measuring surface. In the case of a cold-rolled sheet, the texture in the sheet thickness (direction of the sheet thickness) is not considered to change significantly. However, since the vicinity of the sheet thickness surface is likely to be influenced by shear due to lamination or decarburization, and there is a greater possibility of a change in the microstructure of the steel sheet, the measurement is performed in the half portion thickness. Meanwhile, since it is difficult to perform the measurement on a surface that is exactly the center of the thickness of the steel sheet as a half-thick portion, the specimen
    29/57 can be prepared in such a way that the measuring surface is included in a range of 3% of the plate thickness from the desired position. In a case in which central segregation occurs, the measurement position can be switched to a portion in which segregation and segregation has no influence. In addition, in a case where measurement by X-ray diffraction is difficult, a statistically sufficient number of measurements can be performed by an electronic backscatter standard method (EBSP) or by an electronic channeling method (ECP).
    It is found that the AuEL anisotropy index of uniform elongation is decreased, for example, by controlling the texture (parameter 2X + Y) of a steel sheet as shown in figure 5. The AuEL anisotropy index of uniform elongation refers to the deviation maximum (difference between the maximum and minimum values) of uniform elongation in a case where tensile tests are performed on tensile specimens (tensile specimens according to JIS No. 5) with different sampling directions (the tensile direction in tensile tests) on the plate surface.
    In the following, an embodiment of a method of producing the high-strength cold-rolled steel sheet of the present invention will be described. Figure 6 shows a flowchart of the production method of the high strength steel plate of the modality. The dotted arrows in the flowchart show the preferred optional conditions.
    In the modality, the steel prepared and cast by a common method (cast steel) is cast, the plate obtained is hot rolled, and pickled, cold rolling and annealing are performed on the obtained hot rolled steel plate. Hot rolling can be performed on a common continuous hot rolling line, and annealing after cold rolling can be performed on a continuous annealing line. In addition, the skinpass lamination can be performed on a cold rolled steel plate.
    Unlike steel cast by a common blast furnace method, a steel in which a large amount of scrap is used, such as a
    30/57 electric oven, can be used as cast steel. The slab can be produced using a common continuous process or thin slab casting.
    Meanwhile, after casting, the plate can be hot rolled in the state. However, prior to hot lamination, the plate can initially be cooled to 1000 ° C or less (preferably 950 ° C or less) and then reheated to 1000 ° C or more for homogenization. To sufficiently homogenize the plate and reliably avoid degradation of the resistance, the reheat temperature is preferably 1100 ° C or more. In addition, to prevent the austenite grain size before hot rolling from increasing too much, the reheat temperature is preferably 1300 ° C or less.
    If the finishing temperature of the hot rolling mill is too high when the board is hot rolled, the amount of scale formed increases, and the surface quality and corrosion resistance of the product are adversely influenced. In addition, there are cases where the austenite grain size becomes brutally so as to decrease the fraction of ferrite gases and degrade ductility. In addition, since the austenite grain size becomes brutish, the ferrite and perlite grain sizes also become brutish. Therefore, the finishing temperature of the hot rolling mill is preferably 1000 ° C or less, and more preferably 970 ° C or less. In addition, to avoid the formation of deformed ferrite and maintain favorable steel plate shapes, hot rolling needs to be carried out at a temperature at which the microstructure of a single austenite phase can be maintained, that is, a finishing temperature of 820 ° C or higher. In addition, to reliably avoid lamination in a two-phase region in which ferrite is formed in austenite, hot rolling is preferably carried out at a finishing temperature of 850 ° C or more.
    At this point, to refine the austenite retained in the steel sheet finally obtained, it is effective to refine the microstructure (austenite grain size) in the steel plate during hot rolling. Therefore, the total reduction in the thickness of the last two steps in
    Hot 31/57 is preferably 15% or more. As such, in a case where the total reduction in thickness of the last two steps is 15% or more, the microstructure (for example, ferrite or perlite) of the hot-rolled steel sheet can be sufficiently refined, and the microstructure of the steel sheet becomes uniform so that the elongation over a temperature range of 100 ° C to 250 ° C can increase. In a case where the retained austenite must also be refined, the total reduction in the thickness of the last two steps (the last two passes) is more preferably 20% or more. In addition, to maintain favorable shapes of the steel sheet, and to reduce the loads on the rolling cylinders, the total reduction in thickness of the last two stages (the last two passes) can be 60% or less.
    In the modality, a fine perlite is guaranteed in the hot rolled steel sheet by controlling the winding temperature and the cooling rate (cooling rate after hot rolling) before and after winding. That is, as shown in equations (8) to (11) below, a first average cooling rate CR1 (° C / s) from 750 ° C to 650 ° C is 15 ° C / s to 100 ° C / s, a second rate, CR2 cooling average (° C / s) from 650 ° C to CT winding temperature (° C) is 50 ° C / s or less, a third average CR3 cooling rate (° C / s) since after winding up to 150 ° C it is 1 ° C / s or less, the winding temperature CT (° C) and the first average cooling rate CR1 (° C / s) satisfy equation (11) below.
    15 <CR1 - (8) CR2 <50 - (9) CR3 <1 - (10) 1500 <CR1 x (650-CT) <15000 - (11)
    Here, in a case where the first average cooling rate CR1 is less than 15 ° C / s, the crude perlite increases, and the crude cementite remains on the cold-rolled steel plate. In a case where it is also necessary to refine the perlite and also to accelerate the dissolution of the cementite during annealing, the first average cooling rate CR1 is preferably 30 ° C / s. However, in a case where the first average rate of res
    32/57 CR1 cooling exceeds 100 ° C / s, it is difficult to control subsequent cooling rates. As such, it is necessary to maintain the cooling rate (the first average cooling rate) (CR1) in the frontal cooling zone at a high level during cooling after hot rolling. In the front cooling zone, the hot-rolled steel sheet is cooled to a temperature between the finishing temperature and the winding temperature, so that the microstructure of the steel sheet becomes sufficiently uniform. In addition, in a case where the second average cooling rate CR2 exceeds 50 ° C / s, the transformation does not take place easily, and therefore bainite and fine perlite are not easily formed on hot-rolled steel sheet. Similarly, also in a case where the third average cooling rate CR3 exceeds 1 ° C / s, the transformation does not take place easily, and therefore bainite and fine perlite are not easily formed on hot rolled steel sheet. In such cases, it is difficult to guarantee the necessary amount of austenite in the cold rolled steel sheet. In addition, the lower limits of the second average cooling rate CR2 and the third average cooling rate CR3 are not particularly limited, but are preferably 0.001 ° C / s or more, more preferably 0.002 ° C / s or more, even more preferably 0.003 ° C / s or more, and most preferably 0.004 ° C / s from the point of view of productivity. Additionally, in a case where CR1 x (650 - CT) in equation (11) is less than 1500, the average area of perlite in the hot-rolled steel sheet increases, and the gross cementite remains in the cold-rolled steel sheet . In a case where CR1 χ (650 - CT) exceeds 15000, perlite is not easily formed on hot rolled steel sheet, and therefore it is difficult to guarantee the required amount of austenite on cold rolled steel sheet.
    As such, it is necessary to maintain the cooling rate (the first average cooling rate CR1) in the frontal cooling zone at a high level during cooling after hot rolling. In the front cooling zone, the hot-rolled steel sheet is cooled to a temperature between the finishing temperature and the winding temperature so that the microstructure of the steel sheet becomes sufficiently
    33/57 uniform.
    In addition, the winding temperature CT after cooling in the median cooling zone (cooling at the second average cooling rate CR2) is important. To refine the microstructure of the cold rolled steel sheet, it is necessary to adjust the winding temperature CT in a range of 350 ° C to 600 ° C while satisfying equation (11) above. That is, the winding temperature CT can be determined in the range as shown in figure 7 according to the first cooling rate CR1. Meanwhile, the winding temperature is the average temperature of the steel plate during cooling.
    Here, when the winding temperature CT becomes less than 350 ° C, the microstructure of the hot-rolled steel sheet includes mainly martensite, and the cold-rolling load increases. On the other hand, when the winding temperature exceeds 600 ° C, the gross perlite increases, the average size of ferrite grain in the cold-rolled steel plate increases, and the balance between resistance and hole expansion becomes low.
    To also decrease the cold rolling load, the winding temperature CT is preferably 360 ° C or higher, more preferably 370 ° C or higher, and more preferably 380 ° C or higher. In addition, in a case where the microstructure of the cold rolled steel sheet also needs to be refined, the winding temperature CT is preferably 580 ° C or less, more preferably 570 ° C or less, and more preferably 560 ° C or any less.
    As described above, in the modality, the hot-rolled steel sheet is cooled at the first average cooling rate CR1 from 750 ° C to 650 ° C, cooled at the second average cooling rate CR2 from 650 ° C to the temperature of CT winding, wound at CT winding temperature, and cooled to the third average cooling rate CR3 from the end of the winding to 150 ° C.
    During cold rolling, a thickness reduction of 30% or more is necessary to refine the microstructure after annealing. On the other hand, when the reduction in the thickness of the cold rolling exceeds 85%, the
    34/57 cold rolling load increases due to hardening and productivity is impaired. Therefore, the reduction of the thickness of the cold rolling is in a range of 30% to 85%. Meanwhile, in a case where the microstructure needs to be refined as well, the reduction in thickness is preferably 35% or more, more preferably 40% or more, even more preferably 45% or more, and most preferably still 45% or more. In, a case in which it is also necessary to decrease the load of the cold lamination or to optimize the texture, the reduction in thickness is preferably 75% or less, more preferably 65% or less, and more preferably still 60% or less.
    After cold rolling, the steel sheet is annealed. In the modality, to control the microstructure of the steel sheet, the heating temperature of the steel sheet during annealing and the cooling conditions of the steel sheet after annealing are extremely important.
    When the steel sheet is heated during cooling, the deformed microstructure formed due to cold rolling is recrystallized, and austenite formers, such as C, are concentrated in austenite. In the mode, the heating temperature during annealing is adjusted to a temperature at which ferrite and austenite coexist (point A C i to point Acs).
    When the heating temperature during annealing is less than 750 ° C, the microstructure is not sufficiently recrystallized, and sufficient ductility cannot be obtained. To more reliably improve ductility through recreating, the heating temperature during annealing is preferably 755 ° C or more, more preferably 760 ° C or more, and most preferably 765 ° C or more. On the other hand, when the heating temperature during annealing exceeds 900 ° C, austenite increases, and austenite builders, such as C, do not concentrate sufficiently. To avoid excessive reverse transformation and to concentrate austenite builders more effectively, the heating temperature during annealing is preferably 890 ° C or less, more preferably 880 ° C or less, and more preferably
    35/57
    870 ° C or less. As a result, the stability of austenite is impaired, and it becomes difficult to guarantee the austenite retained after cooling. Therefore, the heating temperature during annealing is 750 ° C to 900 ° C.
    The time (heating time) during which the steel sheet heated to an annealing temperature of 750 ° C to 900 ° C is maintained in a temperature range of 750 ° C to 900 ° C needs to satisfy equation (4) above to sufficiently dissolve the cementite to ensure the amount of C in the austenite. Meanwhile, in equation (4), T (° C) refers to the heating temperature during annealing, and t (s) refers to the heating time during annealing. Here, the average heating temperature T (° C) during annealing is the average temperature of the steel sheet while the steel sheet is heated and maintained in a temperature range of 750 ° C to 900 ° C. In addition, the heating time t (s) during annealing is the time during which the steel sheet is heated and maintained in a temperature range of 750 ° C to 900 ° C.
    That is, during annealing, the annealing parameter P needs to be more than 110 less than 2200. As described above, the annealing parameter P is preferably more than 130, more preferably more than 140, and more preferably even more than 150 In addition, the annealing parameter P is preferably less than 2100, more preferably less than 2000, and more preferably less than 1900.
    Meanwhile, in a case where it is necessary to ensure high uniform elongation in any direction on the plate surface without causing anisotropy in the plane, it is desirable to control the heating during annealing in addition to the CT winding temperature, the reduction in the lamination thickness to cold, and annealing conditions. That is, the average rate of heating is preferably controlled to become 0.1 ° C / s to 7 ° C / s over a range of 600 ° C to 680 ° C on heating during annealing. Recrystallization is significantly accelerated by decreasing the heating rate in the temperature range and increasing the retention time. As a result, the texture of the retained austenite improves. However, in common equipment, it is extremely difficult to control the heating rate.
    36/57 to be extremely slow, and special effects cannot be expected. Therefore, from the point of view of productivity, the average rate of heating is more preferably 0.3% ° C / s or more. When the average heating rate is high, anisotropy is likely to be caused in the texture of the retained austenite while the recrystallization of the ferrite is not sufficiently completed. Therefore, the average rate of heating is more preferably 5 ° C / a or less, even more preferably 3 ° C / s. and most preferably 2.5 ° C / s or less.
    The steel sheet which is annealed at an annealing temperature of 750 ° C to 900 ° C is cooled to a temperature range of 300 ° C to 500C at an average cooling rate of 3 ° C / s to 200 ° C / s . When the average cooling rate is less than 3 ° C / s, perlite is formed on cold rolled steel sheet. On the other hand, when the average cooling rate exceeds 200C / s, it becomes difficult to control the cooling stop temperature. In order to cool the microstructure and effectively proceed with the bainite transformation, the average cooling rate is preferably 4 ° C / s or more, more preferably 5 ° C / s or more, and most preferably still 7 ° C / s or more. In addition, to better control the cooling stop temperature in order to more reliably avoid cementite precipitation, the average cooling rate is preferably 100 ° C / s or less, more preferably 80 ° C / s or less, and even more preferably 60 ° C / s or less.
    The cooling of the steel sheet is stopped, and the steel sheet is kept in a temperature range of 300C to 500C for 15 seconds to 1200 seconds, and then further cooled. The maintenance of the steel sheet in a temperature range of 300 ° C to 500 ° C forms bainite, prevents cementite precipitation, and suppresses the decrease in the amount of C solute in the retained austenite. When the transformation of bainite is accelerated as described above, the area ratio of the retained austenite can be guaranteed
    When the maintenance temperature exceeds 500 ° C, the pearlite is formed. On the other hand, when the maintenance temperature is less than
    37/57
    300 ° C, there are cases where the transformation of martensite occurs, and the transformation of bainite does not happen sufficiently. In addition, when the maintenance time is less than 14 seconds, the transformation of the bainite does not happen sufficiently, and it is difficult to guarantee the retained austenite. On the other hand, when the maintenance time exceeds 1200 seconds, productivity degrades, cementite is precipitated, and ductility degrades.
    To bring about the most suitable bainite transformation, the holding temperature is preferably 330 ° C or more, more preferably 350 ° C or more, and more preferably 370 ° C or more. In order to cause a transformation of the most suitable bainite, the holding temperature is preferably 330 ° C or more, more preferably 350 ° C or more, and more preferably 37 ° C or more. In addition, to more reliably prevent the formation of perlite, the holding temperature is preferably 480 ° C or less, more preferably 460 ° C or less, and more preferably still 440 ° C or less.
    Similarly, to bring about the most suitable bainite transformation, the maintenance time is preferably 30 seconds or more, more preferably 40 seconds or more, and most preferably 60 seconds or more. In addition, to avoid cementite precipitation as much as possible, the maintenance time is preferably 1000 seconds or less, more preferably 900 seconds or less, and more preferably 800 seconds or less.
    The production method of the high strength cold rolled steel sheet of the modality can also be applied to a coated steel sheet. For example, in a case where the method is applied to a galvanized steel sheet, the steel sheet that has been kept at 300 ° C to 500 ° C is dipped in a hot dip galvanizing bath. The temperature of the hot dip galvanizing bath is often 450 ° C to 475 ° C from the point of view of productivity. In addition, for example, in a case where the method is applied to a galvannealed steel sheet, it is also possible to anneal the steel sheet that has been dipped in a hot dip galvanizing bath for bonding. Meantime,
    38/57 in a case where the bonding temperature is not adequate, there are cases where the corrosion resistance degrades due to insufficient bonding or excessive bonding. Therefore, in order to perform an adequate bond while maintaining the microstructure of the base steel, the bonding of a coating is preferably carried out in a range of 400 ° C to 600 ° C. To perform the bonding more sufficiently, the bonding temperature is more preferably 480 ° C or more, even more preferably 500 ° C or more, and more preferably still 520 ° C or more. In addition, to ensure adhesion of the coating while maintaining the microstructure of the base steel more reliably, the bonding temperature is preferably 580 ° C or less, more preferably 570 ° C or less, and even more preferably 560 ° C or less.
    Examples
    The present invention will be described on the basis of examples, but the conditions in the examples are simply an example of the conditions employed to confirm the feasibility and effects of the present invention, and the present invention is not limited to the example of the conditions. The present invention can employ a variety of conditions within the scope of the present invention as long as the objective of the present invention can be achieved.
    A to V steels (the chemical components of the Examples) and aag steels (the chemical components of the Comparative Examples) having the chemical compositions shown in Table 1 were melted and prepared, the steel sheets obtained after cooling and solidification were reheated up to 1200C, and processed under the conditions shown in Tables 2 to 5 (hot rolling, cold rolling, annealing and the like), thus producing steel sheets A1a V1 and a1 to g1. A 0.5% skinpass lamination was performed on each of the annealed steel sheets in order to suppress the elongation of the yield limit.
    Table 1
    Steel Ç Si Mn P s N Al Cr Mo Ni W V Ass others % in large scale THE 0.16 2.3 2.7 0.006 0.002 0.002 0.04 0.5 0.5
    39/57
    B 0.18 1.2 1.7 0.007 0.003 0.002 0.03 Ca: 0.003 Ç 0.11 1.2 1.5 0.006 0.001 0.002 0.034 REMO, 005 D 0.22 1.2 2.2 0.007 0.002 0.003 0.05 AND 0.19 1.3 1.8 0.007 0.003 0.002 0.04 F 0.3 1.3 1.9 0.006 0.001 0.002 0.05 G 0.12 1.3 1.6 0.008 0.001 0.002 0.05 H 0.18 1.8 2.5 0.007 0.003 0.003 0.04 1 0.22 1.8 2.5 0.007 0.003 0.003 0.03 J 0.38 1.5 2.1 0.006 0.002 0.002 0.04 0.6 0.2 K 0.25 1.5 2.9 0.008 0.003 0.005 0.01 Nb: 0.05, Mg: 0.004 L 0.15 0.06 1.5 0.006 0.002 0.003 0.60.12M 0.18 0.1 2.5 0.007 0.003 0.002 0.1 Ca: 0.003 N 0.2 0.4 2.4 0.006 0.001 0.003 0.03 REMO, 005 0 0.22 0.5 2 0.007 0.002 0.002 2.3 B: 0.005 P 0.22 0.15 1.3 0.007 0.003 0.002 10.145 Ti: 0.02, Nb: 0.02 Q 0.25 0.5 1.9 0.006 0.002 0.002 0.90.14R 0.3 0.4 1.2 0.008 0.003 0.002 0.03 Ti: 0.07 s 0.3 0.07 1.6 0.006 0.001 0.003 1.40.25T 0.25 0.5 1.7 0.007 0.001 0.004 1.40.15u 0.22 0.09 0.7 0.006 0.002 0.002 1.1 0.3 0.1 0.2 V 0.22 0.1 1.4 0.04 0.018 0.003 1.10.2 Zr: 0.005 The 0.42 1.55 2 0.006 0.001 0.002 0.03 B 0.05 1.2 2 0.007 0.001 0.003 0.035 ç 0.22 1.2 1.25 0.06 0.04 0.003 0.040.2d 0.25 3 1 0.006 0.001 0.0025 0.040.22and 0.25 1.15 6 0.007 0.001 0.004 0.035 f 0.3 0.001 1.4 0.008 0.001 0.004 0.001 g 0.3 0.09 1.2 0.008 0.003 0.002 30 * 4
    Underlined cells do not meet the conditions according to the present invention.
    40/57
    Table 2
    Steel sheet Steel Hot rolling Cooling and winding s Reduction in the thickness of the last two stages Finishing temperature CR1 CR2 CT CR1x (650-CT) CR3 % ° C ° C / s ° C / s ° c ° c7s ° C / s pm TO 1 THE 18 881 60 29 550 6000 0.01 15 A2 THE 20 885 40 33 550 4000 0.008 17 A3 THE 10 885 50 31 550 5000 0.008 29 B1 B 20 890 60 28 550 6000 0.008 12 B2 B 20 890 60 32 540 6600 0.008 11 B3 B 22 895 50 30 480 8500 0.006 5 C1 Ç 19 894 40 34 550 4000 0.01 19 C2 Ç 18 897 50 40 580 3500 0.006 20 D1 D 16 888 40 36 540 4400 0.01 22 D2 D 16 880 60 33 480 10200 0.006 11 D3 D 20 888 60 36 530 7200 0.009 10 E1 AND 22 887 40 32 550 4000 0.008 14 E2 AND 19 890 60 40 550 6000 0.01 14 F1 F 18 880 40 29 550 4000 0.01 20 F2 F 15 895 50 25 550 5000 0.01 22 F3 F 20 885 60 39 450 12000 0.009 2 F4 F 22 880 60 29 420 13800 0.008 11 G1 G 19 901 50 33 550 5000 0.008 16 G2 G 18 900 40 36 520 5200 0.008 17 H1 H 22 910 50 27 480 8500 0.01 5 H2 H 19 900 30 33 520 3900 0.007 19 H3 H 18 900 60 35 520 7800 0.006 12 H4 H 22 890 10 27 550 1000 0.007 29 11 I 19 912 60 36 550 6000 0.008 14 I2 I 18 890 40 32 520 5200 0.006 17
    41/57
    J1 J 16 860 50 40 480 8500 0.007 14 J2 J 16 892 40 31 650 0 0.007 30 K1 K 20 845 60 40 540 6600 0.008 11
    Underlined cells do not meet the conditions according to the present invention.
    Table 3
    Steel sheet Steel Hot rolling Cooling and winding s Reduction in the thickness of the last two stages Finishing temperature CR1 CR2 CT CR1x (650-CT) CR3 % ° C ° C / s ° C / s ° C ° C 2 / s ° C / s pm 2 L1 L 22 891 50 40 550 5000 0.008 11 L2 L 19 900 40 29 560 3600 0.01 19 M1 M 18 836 50 27 560 4500 0.008 18 M2 M 16 860 30 36 700 -1500 0.008 36 N1 N 16 849 60 27 550 6000 0.009 18 N2 N 20 840 60 40 550 6000 0.006 12 O1 O 22 935 40 32 580 2800 0.007 16 02 O 22 910 50 40 540 5500 0.006 11 P1 P 19 906 60 32 480 10200 0.007 7 P2 P 18 900 60 30 550 6000 0.009 15 Q1 Q 16 878 50 32 580 3500 0.008 23 Q2 Q 16 885 40 25 540 4400 0.009 22 R1 R 20 864 50 39 480 8500 0.009 8 R2 R 22 875 10 32 550 1000 0.007 29 S1 s 18 888 40 36 550 4000 0.009 20 S2 s 22 895 50 32 550 5000 0.009 11 T1 T 19 908 60 31 580 4200 0.01 16 T2 T 18 895 60 26 540 6600 0.008 14 U1 u 16 918 50 34 480 8500 0.008 14
    42/57
    V1 V 16 903 40 28 530 4800 0.007 21 to 1 The 18 858 50 28 550 5000 0.008 17 b1 B 18 901 50 26 550 5000 0.007 17 c1 ç 18 905 50 32 550 5000 0.006 17 d1 d 18 901 50 33 550 5000 0.01 17 e1 and 18 879 50 37 550 5000 0.01 17 f1 f 18 890 50 31 550 5000 0.008 17 gi J 18 893 50 36 550 5000 0.009 17
    Underlined cells do not meet the conditions according to the present invention.
    Table 4
    Plate Blade- Heating and annealing cooling and maintenance P Link of steel chillingreduction Rate of Temperatu- Time to Rate Tem- Has-Temper-in the heated of recovery annealing in rura po oftura ofweight ment zimentocooled in manuLinkamen- manu intention to intention % ° C / s ° C s ° C / s ° C s° Cwithout TO 1 50 0.5 800 86 40 400 400 167 coatedmentwithout A2 45 0.5 780 90 150 400 300 154 coatedmentwithout A3 45 2.2 780 30 150 400 100 70 coatedment B1 60 1.9 840 85 40 400 300 218 440 B2 50 1.6 850 90 4 450 40 236 440 B3 45 2 980 70 40 380 40 474 410 C1 55 0.6 800 60 40 425 300 133 460
    43/57
    02 60 1.2 850 90 4 450 40 145 460 D1 50 1.6 775 90 50 400 300 119 uncoated D2 45 2.4 820 80 100 425 300 217 uncoated D3 50 2.2 660 80 100 380 300 189 uncoated E1 45 2 800 90 40 425 300 187 uncoated E2 55 1.8 800 80 100 425 300 194 uncoated F1 60 1.7 775 85 50 400 200 134 uncoated F2 55 1.8 840 70 100 425 300 117 uncoated F3 60 30 820 70 100 220 300 598 uncoated F4 50 0.5 800 65 100 550 300 198 uncoated G1 45 1.4 800 90 40 425 300 172 uncoated
    44/57
    G2 50 1.4 800 80 100 400 300 146 uncoated H1 45 2.3 775 90 50 400 150 357 uncoated H2 55 2 840 90 100 425 200 144 uncoated H3 90 1.8 820 80 120 400 1400 200 uncoated H4 55 0.6 800 80 120 425 200 94 uncoated 11 60 1.7 775 90 50 400 300 186 uncoated I2 70 1.9 780 80 100 380 200 147 uncoated J1 45 2.2 800 80 40 380 300 173 uncoated J2 50 2.2 800 90 40 425 300 95 uncoated K1 45 1 780 90 40 400 400 230 uncoated
    Underlined cells do not meet the conditions of the present invention.
    45/57
    Table 5
    Steel sheet Cold rolling Heating and annealing cooling and maintenance P Linkreduction Rate Tem- Time Rate Tem- TimeTem-in the in rature of in in rature of inrature ofweight that- annealed annealed cooled manu manuLink cement ment ment forgive intention intention % ° C / s ° C s ° C / s ° C s° C L1 55 2.1 850 90 4 440 40 202 470 L2 60 1.2 775 90 40 440 400 156 470 M1 50 0.8 800 90 4 425 40 171 500 M2 45 1.8 800 90 40 380 300 87 500 N1 50 0.7 840 90 4 425 40 182 500 N2 45 1.1 820 90 40 450 300 265 500 01 55 2.2 800 90 4 400 40 190 500 02 50 0.7 800 90 40 425 300 296 500 P1 45 1.1 800 90 4 430 40 450 520 P2 50 2 800 90 40 430 400 207 520 Q1 45 1.8 800 90 4 425 40 137 520 02 55 1 775 90 50 430 350 136 520 R1 60 1.6 800 90 4 400 40 401 500 R2 50 1.8 820 90 40 425 300 109 500 S1 45 0.7 840 90 4 380 40 163 500 S2 50 1.2 840 90 40 380 300 287 500 T1 45 0.7 780 90 4 425 40 191 520 T2 55 1.3 775 90 40 440 350 213 520 U1 60 1.9 780 90 4 425 40 221 520 V1 55 0.8 830 90 4 380 40 152 520without to 1 50 1.5 800 90 40 400 300 179 coatedment
    46/57
    b1 50 1 800 90 40 400 300 179 uncoated c1 50 1.7 800 90 4 400 300 179 500 d1 50 1.1 800 90 40 400 300 179 500 e1 50 0.6 800 90 4 400 40 179 uncoated f1 50 1.4 800 90 40 400 300 179 uncoated gi 50 1.1 800 90 40 400 300 179 500
    Underlined cells do not meet the conditions of the present invention.
    Steel sheets produced in the above manner were evaluated as follows. A JIS No. 5 specimen in a C direction (a direction perpendicular to the rolling direction) was prepared, a tensile test was performed at 25 ° C, and the TS tensile strength, the total elongation tEL and the elongation uniform uEL were evaluated. Similarly, a JIS specimen No. 5 in direction C was immersed in a 150C oil bath, a tensile test was performed, and the elongation (total elongation) at 15C tELion was evaluated. Here, the stretch at 150 ° C was evaluated as a warm band stretch. In addition, for each of the thin steel sheets, a characteristic index E obtained from equation (12) below was computed from the tensile strength TS and the elongation at 150 ° C tELiôoE = tEL- iso + 0.027TS - 56.5 - (12)
    Meanwhile, equation (12) will be described below.
    In addition, the expansion of hole λ was evaluated using hole expansion tests.
    In addition, a cross section of the steel sheet in the rolling direction or a cross section perpendicular to the rolling direction47 / 57 tion was observed using an optical microscope at an amplification of 500 times to 1000 times, and the image obtained was evaluated using an image analyzer. The average area S of perlite in the hot-rolled steel sheet and the microstructure in the cold-rolled steel sheet (the area ratio and the average grain size of the ferrite, the area ratio of the bainite, the average grain size of the retained austenite, martensite area ratio, and temperate martensite area ratio) were quantified.
    Meanwhile, in a case where ferrite, bainite, perlite, and retained austenite were evaluated, the cross section of the measurement specimen was etched using a Nital reagent. In a case where martensite was evaluated, the cross section of the measurement specimen was etched using a La Pera reagent. In a case where cementite was evaluated, the cross section of the measurement specimen was etched using a picral agent.
    Here, the average sizes of ferrite grains and retained austenite are evaluated, for example, by observing arbitrary areas in the cross section of the steel sheet using an optical microscope, measuring the number of grains (ferrite grains or austenite grains) in a range of 1000 μιΐΊ 2 or more, and obtaining the equivalent average diameter of the circle.
    In addition, to obtain the average grain size, the aspect ratio, and the number per unit area of the cementite particles on the cold rolled steel plate, a replica sample was prepared, and an image was obtained using a microscope. emission and transmission (TEM). The area of 20 to 50 cementite particles in the image was obtained, converted to an area of a cementite particle, and the average cementite particle size was evaluated using an equivalent average circle diameter. In addition, the length of the short axis and the length of the long axis of the cementite were measured in order to obtain an aspect ratio, and the spheroidization ratio above was computed. Similarly, the number of cementite particles having an aspect ratio of 1 to 3 was divided by the evaluation area, thus computing the number of cementite particles per unit area (density). Meanwhile, for ce observation
    48/57 lies, for example, an optical microscope and a scanning electron microscope (SEM) can be used appropriately depending on the particle size distribution of cementite.
    As shown below, the retained austenite area ratio was obtained by X-ray diffraction described in Unexamined Japanese Patent Application, First Publication No. 2004-269947.
    A surface at a depth of 7/16 of the plate thickness from the base plate surface (the surface of the steel plate or the interface between the coating and the steel plate) was chemically polished, and then the diffraction intensity Ia (200) in (200) of ferrite, the diffraction intensity Ia (211) in (211) of ferrite, the diffraction intensity Ιγ (220) in (220) of austenite, and the diffraction intensity Ιγ (311) in (311) of austenite were measured by X-ray diffraction using a Mo tube (ΜοΚα). The Vy area ratio (%) of retained austenite was obtained from the diffraction intensity (integrated intensity) using equation (13) below.
    Vy = 0.25 x {ly (220) / (1.35 x la (200) + ly (220)) + ly (220) / (0.69 x la (211) + ly (220)) + ly (311) / (1.5 x la (200) + ly (311)) + ly (311) / (0.69 x la (211) + ly (311))} - (13)
    In addition, for austenite phases retained in the half-thick portion of the steel layer, each mean value of the random intensity ratios of an orientation {100} <001>, of the orientation {110} <111>, of the orientation {110} <001 >, and the guidance group {110} <111> to {110} <011> was measured as follows. Initially, the steel plate was mechanically polished, polished with a leather disc, and then, furthermore, electrolytically polished to remove stresses, and X-ray diffraction was performed using a specimen that was adjusted so that the portion half-thickness became the measuring surface. Meanwhile, X-ray diffraction of a standard specimen having no accumulation in a specific orientation was also performed under the same conditions as the measurement specimen. Next, the guidance distribution (ODF) functions were obtained by a series expansion method based on the pole figures of
    49/57 {200}, {311}, and {220} of the austenite phases that were obtained through X-ray diffraction. Each mean value of the random intensity ratios of the {100} <001> orientation, of the {110} orientation <112>, the guidance {110} <001>, and the guidance group {110} <112> to {110} <001> was obtained at 5 from the ODF. 2X + Y in equation (7) above and {110} <111> / {110} <001>
    were computed from the mean values of the random intensity ratios.
    The results are shown in Tables 6 to 9. In Tables 6 to 9, ferrite, retained austenite, bainite, martensite, tempered martensite, ce10 mentita are abbreviated by F, γ, B, Μ, M ’, and Θ, respectively.
    Table 6
    reason of reason of reason of reason of area ratio reason of size size sizein special reason density Steel sheet F + B area areadey area ofM areadeF inB + M area ofP graindeF graindey particle gnawed of the% % % % % % pm pm pm % particles / pm TO 1 60 17 9 50 10 0 5.8 2.4 0.3 73.9 0.051 A2 60 17 8 40 20 0 4.8 2.5 0.3 79.3 0.045 A3 55 18 10 38 17 0 15.2 8.0 12 20.0 0.170 B1 62 11 3 40 22 0 3.9 2.5 0.2 79.3 0.050 B2 62 11 6 30 32 3 5.0 3.5 0.2 57.7 0.057 B3 25 1 23 0 54 0 6.5 4.1 0.1 I Q 0.200 C1 67 10 4 40 27 0 2.9 2.4 0.3 84.2 0.031 C2 66 10 2 17 49 2 5.0 3.5 0.3 57.7 0.033 D1 53 14 11 40 13 0 3.8 2.5 0.4 79.3 0.042 D2 53 14 5 35 18 0 5.4 2.4 0.3 84.2 0.050 D3 100 0 0 100 25 0 8.31.0 90.0 0.700 E1 60 12 3 40 20 0 4.1 2.4 0.3 84.2 0.058 E2 61 12 3 40 21 0 7.4 2.4 0.3 842 0.058 F1 65 19 5 55 10 0 7.2 2.7 0.5 73.6 0.052 F2 54 18 5 27 27 0 6.8 2.4 0.5 84.2 0.049
    50/57
    F3 54 1 5 40 34 0 9.4 3.1 0.1 64.4 0.057 F4 74 5 5 40 34 0 2.9 1.8 1.4 70.0 0.018 G1 67 10 2 43 24 0 3.6 2.4 0.2 84.2 0.043 G2 67 10 2 55 12 0 6.4 2.5 0.3 79.3 0.040 H1 58 16 7 30 28 0 8.3 2.9 0.1 69.6 0.040 H2 58 16 7 20 38 0 4.4 2.6 0.3 78.2 0.045 H3 77 0 7 37 40 0 3.1 2.0 12 87.1 0.013 H4 48 15 7 30 18 0 4.5 2.6 U 78.2 0.014 11 50 16 8 37 13 0 6.3 2.5 0.3 79.3 0.030 I2 52 16 7 38 14 0 7.2 2.9 0.4 70.0 0.051 J1 46 19 8 35 11 0 6.9 2.7 0.8 75.3 0.038 J2 47 21 7 33 14 0 3.0 2.4 2.0 84.2 0.200 K1 39 24 10 29 10 0 9.2 2.4 0.3 73.9 0.050
    Underlined cells do not meet the conditions of the present invention.
    Table 7
    reason of reason of reason of reason of area ratio reason of size size sizein special reason density Steel sheet F area+ B areadey area ofM areadeF inB + M ' area ofP graindeF graindey particle gnawed of the% % % % % % pm pm pm % particles / pm L1 68 10 4 28 40 1 5.4 3.5 0.2 56.4 0.052 L2 68 10 2 55 13 0 3.4 2.2 0.3 81.2 0.037 M1 53 14 10 40 13 3 9.4 3.7 0.3 54.5 0.047 M2 51 15 6 40 11 0 5.3 2.7 12 75.3 0.170 N1 51 15 12 23 28 3 5.2 3.7 0.3 54.5 0.052 N2 48 15 7 34 14 0 4.7 2.2 0.2 89.2 0.067 01 56 13 9 40 16 2 7.0 3.9 0.4 51.3 0.051 02 56 13 5 40 16 0 3.0 2.4 0.3 84.2 0.067 P1 63 11 5 46 17 1 11.0 3.6 0.2 55.1 0.094 P2 62 12 3 30 32 0 7.1 2.2 0.3 79.4 0.056
    51/57
    Q1 53 14 11 40 13 2 5.8 3.7 0.5 54.5 0.044 02 54 14 5 39 15 0 4.2 2.3 0.5 87.5 0.043 R1 57 17 9 37 20 2 4.0 3.9 0.3 51.3 0.040 R2 57 17 4 28 29 0 6.8 2.4 14 84.2 0.190 S1 52 19 11 35 17 4 9.5 4.1 0.4 67.0 0.056 S2 51 20 6 37 14 0 4.2 2.7 0.3 75.3 0.040 T1 56 13 9 40 16 2 6.3 3.7 0.4 54.5 0.054 T2 55 13 5 38 17 0 3.8 2.2 0.4 89.6 0.057 U1 71 9 3 58 13 2 7.9 3.7 0.3 54.5 0.057 V1 62 12 6 49 13 3 6.5 4.1 0.4 60.0 0.047 to 1 47 21 15 32 15 0 5.9 2.5 14 79.3 0.180 b1 69 1 2 32 37 0 4.0 2.5 0.1 79.3 0.042 c1 61 12 3 50 11 2 5.4 2.5 0.3 79.3 0.053 d1 56 13 4 45 11 0 6.4 2.5 0.2 79.3 0.030 e1 37 5 23 20 17 0 8.9 3.9 0.4 51.3 0.010 fl 58 1 4 37 21 0 5.6 2.5 2.0 79.3 0.200 gi 53 19 5 20 33 0 5.2 2.5 0.2 79.3 0.050
    Underlined cells do not meet the conditions of the present invention.
    Table 8
    Steel 2X + Y {110} <111> /{110} <001> TS tel tel-i5o AND uEL λ N / mm 2 % %% % TO 1 8.0 1.4 1312 17.6 23.0 1.9 15.4 34.7 A2 8.1 2.2 1300 17.7 23.1 1.7 14.4 37.5 A3 5.0 2.1 1380 12.9 13.0 -6.3 9.9 30.0 B1 8.4 2.2 753 28.4 41.8 5.7 24.3 38.2 B2 7.9 1.8 773 27.7 40.6 5.0 23.3 38.8 B3 8.4 1.3 1523 12.0 12.0 -3.4 10.0 15.0 C1 1.5 1.6 614 34.1 45.0 5.0 29.1 39.2 C2 6.7 2.1 654 32.2 42.5 3.6 26.9 39.8
    52/57
    D1 6.2 2.1 1044 21.3 30.0 1.7 18.7 35.9 D2 9.2 1.4 1029 21.6 31.5 2.7 18.6 36.6 D3 6.9 1.6 1100 14.4 20.7 -6.1 10.9 58.3 E1 11.1 1.7 824 26.2 38.1 3.8 22.7 37.4 E2 6.3 2.0 790 27.2 39.8 4.6 23.6 37.5 F1 8.2 1.5 1013 23.3 33.3 4.2 20.2 34.2 F2 6.2 2.0 990 23.7 34.0 4.2 21.4 33.1 F3 4.9 1.5 1009 15.0 18.1 -11.1 9.0 38.0 F4 10.7 7.4 992 15.7 25.8 -3.9 8.2 32.0 G1 10.2 1.7 634 33.1 45.1 5.7 29.5 37.4 G2 6.0 2.2 620 33.8 45.9 6.2 28.3 39.9 H1 7.0 2.2 1189 19.1 26.6 2.2 16.7 35.3 H2 7.3 1.6 1188 19.1 25.6 1.2 15.5 38.0 H3 7.3 2.2 1200 15.0 15.0 2.9.1 9.0 30.0 H4 10.7 2.1 1170 17.4 18.4 -6.6 14.3 28.0 11 6.8 1.9 1239 18.4 25.9 2.8 15.0 37.8 I2 6.3 1.5 1199 19.0 26.5 2.3 15.4 37.9 J1 8.9 1.2 1230 19.3 28.2 4.9 16.8 33.9 J2 6.3 2.0 1210 18.1 20.1 -3.7 15.9 26.0 K1 4.8 1.2 1433 17.6 23.5 5.7 15.6 31.2
    Underlined cells do not meet the conditions of the present invention.
    Table 9
    Steel 2X + Y {110} <111> /{110} <001> TS tel tEL 150 AND uEL λ N / mm 2 % %% % L1 7.8 1.4 601 34.8 51.0 10.8 31.0 37.5 L2 9.1 2.2 599 34.9 49.2 8.9 31.2 37.5 M1 9.6 1.6 1020 21.8 29.9 0.9 19.1 36.0 M2 5.3 1.2 1080 19.7 21.7 t 5.6 16.5 23.0 N1 7.9 2.2 1088 20.6 28.7 1.5 17.7 36.3
    53/57
    N2 6.6 2.0 1170 19.4 27.0 2.1 15.7 38.1 O1 6.1 1.9 941 23.3 33.9 2.8 20.1 36.9 02 7.8 1.1 950 23.1 34.1 3.3 19.3 38.2 P1 8.4 1.7 739 28.9 45.4 8.9 23.9 39.6 P2 9.1 1.7 780 27.5 41.7 6.2 23.5 38.2 Q1 7.4 1.2 1039 21.4 31.1 2.6 17.8 37.9 Q2 8.2 1.2 1001 22.1 32.2 2.8 18.4 38.0 R1 9.5 1.1 927 25.0 37.7 6.2 22.9 33.0 R2 8.3 1.4 900 23.7 25.7 -6.5 20.9 18.0 S1 6.7 2.2 1065 22.3 31.9 4.1 19.6 33.5 S2 7.1 1.8 1100 21.7 31.4 4.6 19.8 32.1 T1 8.2 2.2 951 23.1 34.7 3.8 18.9 38.9 T2 4.8 1.8 960 22.9 34.4 3.9 19.4 37.5 U1 6.5 1.3 515 40.1 65.8 23.2 34.5 39.4 V1 7.5 1.6 779 27.6 41.2 5.7 22.8 39.5 to 1 8.2 2.0 1220 15.0 20.6 -3.0 12.8 30.0 b1 5.5 1.6 551 31.2 31.2 -10.4 8.7 39.0 c1 8.4 2.7 807 16.7 25.0 -9.7 12.0 34.0 d1 5.3 2.7 942 17.3 26.9 t4.1 13.4 31.0 e1 7.1 1.1 1510 8.9 15.4 -.0.4 7.0 32.0 f1 9.6 1.7 881 18.8 20.8 -11.9 12.0 26.0 gi 9.0 2.7 1044 17.7 26.415.2 29.0
    Underlined cells do not meet the conditions of the present invention
    The steel sheets of the Examples were all excellent in terms of balance between strength and forming capacity (elongation and bore expansion). In addition, the steel plate E2 had a small anisotropy in the plane during forming compared to the steel plate E1.
    For the A3 steel sheet, since the annealing conditions (annealing parameter P) did not satisfy equation (4) above, 10 the average cementite particle size exceeded 1 pm, and the esfe ratio
    54/57 gelled cementite was less than 30%. Therefore, sufficient forming capacity cannot be ensured. In addition, the total reduction in the thickness of the last two stages in hot rolling was small, and the average size of the retained austenite grains was large compared to steel sheets A1 and A2.
    For steel plate B3, since the average annealing heating temperature (annealing temperature) exceeded 900 ° C, the retained austenite area ratio was less than 2%, the martensite area ratio exceeded 20%, and the spheroidized ratio of cementite was less than 30%. Therefore, the tensile strength TS has increased excessively, and sufficient forming capacity cannot be guaranteed.
    For steel plate D3, since the annealing heating temperature was less than 750 ° C, the area ratio of the retained austenite was less than 2%. Therefore, sufficient forming capacity cannot be guaranteed.
    For steel plate F3, since the retention temperature was less than 300 ° C, the area ratio of the retained austenite was less than 2%. Therefore, sufficient forming capacity cannot be guaranteed.
    For steel sheet F4, since the holding temperature exceeded 500 ° C, the average cementite particle size exceeded 1 μητ Therefore, sufficient forming capacity cannot be guaranteed.
    For H3 steel sheet, since the reduction in cold rolling thickness exceeded 85%, and the retention time exceeded 1200 seconds, the area ratio of the retained austenite was less than 2%, and the average particle size of cementite exceeded 1 μιτι. Therefore, sufficient forming capacity cannot be guaranteed.
    For steel sheets H4 and R2, since the average cooling rate in the frontal cooling zone was less than 15 ° C, and the annealing conditions did not satisfy equation (4) above in cooling after hot rolling, the average particle size of cementite ex
    55/57 yielded 1 gm. Therefore, sufficient forming capacity cannot be guaranteed.
    For steel plates J2 and M2, since the winding temperature exceeded 600C, and the cooling conditions did not satisfy equation (4) above, the average cementite particle size exceeded 1 μηΊ. Therefore, sufficient forming capacity cannot be guaranteed.
    For a1 to g1 steel sheets that were produced using a to g steels, the chemical components were not suitable. For steel sheet a1 (steel a), the amount of C exceeded 0.40%, and the average cementite particle size exceeded 1%. For steel plate b1 (steel b), the amount of C was less than 0.10%, and the ratio of retained austenite area was less than 2%. For steel sheet c! (steel c), the amount of P exceeded 0.05%, and the amount of Si exceeded 0.02%. For steel sheet d1 (steel d), the amount of Si exceeded 2.5%. For the e1 steel plate (e steel), the amount of Mn exceeded 4.0%, and the martensite area ratio exceeded 20%. For the steel sheet f1 (steel f), the amount of Si was less than 0.005%, the austenite area ratio was less than 2%, and the average cementite particle size exceeded 1 μηη. For steel plate g1 (steel g), the amount of Al exceeded 2.5%, and the amount of Mo exceeded 0.3%. Therefore, for these steel sheets a1 to g1, the balance between strength and conformation has deteriorated.
    Here, the relationship between tensile strength and elongation at 150C will be described. Figure 8 is a view showing the relationship between TS tensile strength (N / mm 2 ) and elongation at 150 ° C tELi 50 (%). Meanwhile, in figure 8, the tensile strength values TS and the elongation at 150 ° C tELion are used, which are shown in Tables 6 to 9.
    As is clear from figure 8, it can be confirmed that, in a case in which the same tensile strength of Comparative Examples was obtained, the steel sheets of the Examples had an extremely high elongation at 150 ° C compared with the Comparative Examples.
    In addition, the steel sheets of the Examples included in the area
    56/57 above the straight line of equation (13) shown in figure 8.
    tELiso = -0.027TS + 56.5 ··· (13)
    The straight line indicates the balance between strength and forming capacity, and is thus obtained from the results in figure 8.
    The characteristic index E shown by equation (12) above in Tables 4 and 5 refers to an index showing the balance between resistance and stretching as described above. When the value of the characteristic index E is positive, the values of tensile strength and elongation at 150 ° C of the steel plates are included in the area above equation (13) in figure 8. When the value of the characteristic index E is negative , the values of tensile strength and elongation at 150 ° C of steel sheets at 150 ° C are included in the area below equation (13) in figure 8.
    Meanwhile, the examples above are simply exemplified configurations of the present invention, and for the steel sheet according to the present invention and the method of production thereof, a variety of modifications can be added within the scope of the claims.
    For example, a variety of treatments can be performed on the steel sheet according to the present invention as long as the treatments do not change the size of the cementite. That is, the steel sheet according to the present invention can be any cold rolled steel sheet as it is cold rolled, a galvanized steel sheet, a galvannealed steel sheet, and an electrolysis coated steel sheet, and even in in a case where a variety of treatments are performed, the effects of the present invention can be obtained.
    In addition, the present invention is rarely influenced by the casting conditions. For example, a casting method (continuous casting or conventional casting) or a difference in slab thickness has little influence, and even in a case where a special casting and hot rolling method, such as thin slabs, is used, the effects of the present invention can be obtained.
    Industrial Applicability
    According to the present invention, it is possible to transmit a
    57/57 favorable forming capacity for an object to be formed when a process, such as forming using a press, is performed, and to obtain favorable forming capacity even in the case where the weight of the body structure of automobiles is decreased using a high-strength steel plate.
    权利要求:
    Claims (18)
    [1]
    1. Cold rolled steel sheet, characterized by the fact that it consists, in mass%,
    C: 0.10% to 0.40%;
    Mn: 0.5% to 4.0%;
    Si: 0.005% to 2.5%;
    Al: 0.005% to 2.5%;
    Cr: 0% to 1.0%;
    optionally one or more types of elements between:
    Mo: 0.01% to 0.3%;
    Ni: 0.01% to 5%;
    Cu: 0.01% to 5%;
    B: 0.0003% to 0.003%;
    Nb: 0.01% to 0.1%;
    Ti: 0.01% to 0.2%;
    V: 0.01% to 1.0%;
    W: 0.01% to 1.0%;
    Ca: 0.0001% to 0.05%;
    Mg: 0.0001% to 0.05%;
    Zr: 0.0001% to 0.05%; and
    REM: 0.0001% to 0.05%; and an iron balance and the inevitable impurities, where the amount of P is limited to 0.05% or less, the amount of S is limited to 0.02% or less, the amount of N is limited to 0.006% or less , its microstructure includes 2% to 30% of austenite retained by percentage of area, martensite is limited to 20% or less by percentage of area in the microstructure, an average particle size of cementite in the microstructure is 0.01 μηη a 1 μηη, and
    30% to 100% of cementite has an aspect ratio of 1 to 3.
    Petition 870180032976, of 04/24/2018, p. 4/12
    [2]
    2/5
    2. Cold rolled steel sheet according to claim
    1, characterized by the fact that the sum (Si + Al) of the amount of
    Si and the amount of Al is 0.5% to 2.5% by weight%.
    [3]
    3. Cold rolled steel sheet according to claim
    1, characterized by the fact that the average grain size of the retained austenite is 5 gm or less.
    [4]
    4. Cold rolled steel sheet according to claim
    1, characterized by the fact that the microstructure includes, in percentage of area, 10% to 70% of ferrite.
    [5]
    5. Cold rolled steel sheet according to claim
    1, characterized by the fact that the microstructure includes, by percentage of area, 10% to 70% of ferrite and bainite in total.
    [6]
    6. Cold rolled steel sheet according to claim
    1, characterized by the fact that the microstructure includes, by percentage of area, 10% to 75% of bainite and tempered martensite in total.
    [7]
    7. Cold rolled steel sheet according to claim
    1, characterized by the fact that the average grain diameter of the ferrite is 10 gm or less.
    [8]
    8. Cold rolled steel sheet according to claim 1 characterized by the fact that 0.003 to 0.12 cementite particle having an aspect ratio of 1 to 3 are included in an area of 1 μηη 2 .
    [9]
    9. Cold rolled steel sheet according to claim 1 characterized by the fact that in a central portion of the thickness
    Petition 870180032976, of 04/24/2018, p. 5/12
    3/5 sura of the plate, the X-rays of the random intensity X of the orientation {100} <001> of the retained austenite and the average value Y of the random intensity ratio of the group of orientations {110} <111> to {110 } <001> of the retained austenite satisfy the equation (14) below.
    4 <2X + Y <10 - (14)
    [10]
    10. Cold-rolled steel sheet according to claim 1, characterized by the fact that, in a central portion of the sheet thickness, the ratio of the random intensity ratio of the {110} <111> orientation of the retained austenite for the random intensity ratio of the {110} <001> orientation of the retained austenite is 3.0 or less.
    [11]
    11. Cold rolled steel sheet according to claim 1, characterized in that it also comprises a zinc coating on at least one surface of the same.
    [12]
    Cold-rolled steel sheet according to claim 1, characterized in that it also comprises a galvanized coating on at least one of the surfaces thereof.
    [13]
    13. Production method of cold rolled steel sheet as defined in claim 1, characterized by the fact that it comprises:
    a first process in which the plate having the chemical composition as defined in claim 1 or 2, is hot rolled at a finishing temperature of 820Ό or higher in order to produce a hot rolled steel sheet;
    a second process in which, after the first process, the hot-rolled steel sheet is cooled and wound at a CT ° C winding temperature of 350 ° C to 600 ° C;
    a third process in which the hot rolled steel sheet that underwent the second process is cold rolled in a thickness reduction of 30% to 85% in order to produce a cold rolled steel sheet;
    a fourth process in which, after the third process, the cold-rolled steel sheet is heated and annealed to an average temperature of
    Petition 870180032976, of 04/24/2018, p. 6/12
    4/5 heating from 750Ό to 900X3;
    a fifth process in which the cold rolled steel sheet that underwent the fourth process is cooled to an average cooling rate of SO / s to 200Ό / 3 and maintained in a temperature range of 300Ό to 500Ό for 15 seconds to 1200 seconds , and a sixth process in which the cold rolled steel sheet that underwent the fifth process is cooled, in which in the second process, a first average cooling rate CR1 O / s from 750 ° C to 650 ° C is 15 ° C / s to 100 ° C / s, a second average cooling rate CR2 ° C / s of 650 ° C until the winding temperature CT ° C is 50 ° C / s or less, a third average cooling rate CR3 ° C / s after winding at 150 ° C is 1 ° C / s or less, and the winding temperature CT ° C and the first average cooling rate CR1 ° C / s satisfy equation (15) below, and in the fourth process , in a case where the quantities of Si, Al, and Cr are represented by [Si], [Al] and [Cr] in terms of% by mass, respectively, the average area S pm 2 of perlite included in the hot rolled steel plate that underwent the second process, the average heating temperature T ° C, and the heating time ts satisfy the relationship of equation (16) below.
    1500 <CR1 x (650 -CT) <15000 ··· (15)
    2200> T x log (t) / (1 + 0.3 [Si] + 0.5 [AI] + [Cr] + 0.5S)> 110 ··· (16)
    [14]
    14. Method of production of cold rolled steel sheet according to claim 13, characterized by the fact that the total reduction in thickness of the last two steps in the first process is 15% or more.
    [15]
    15. Production method of cold rolled steel sheet according to claim 13, characterized by the fact that the cold rolled steel sheet that underwent the fifth process and must undergo the sixth process is coated with zinc.
    [16]
    16. Production method of cold rolled steel sheet of
    Petition 870180032976, of 04/24/2018, p. 7/12
    5/5 according to claim 13, characterized by the fact that the cold rolled steel sheet that underwent the fifth process and must undergo the sixth process is galvanized and annealed at 400 ° C to 600 ° C for bonding ..
    5
    [17]
    17. Production method of cold rolled steel sheet according to claim 13, characterized by the fact that the average heating rate of 600 ° C to 680 ° C in the fourth process is 0.1 ° C / s to 7 ° C / s.
    [18]
    18. Production method of cold rolled steel sheet 10 according to claim 13 characterized by the fact that, before the first process, the plate is cooled to 1000Ό or less and reheated to 1000Ό or more.
    Petition 870180032976, of 04/24/2018, p. 12/12
    1/6
    FIG. 2
    Average particle diameter (μιτι)
    2/6
    FIG. 3
    Average particle diameter (pm)
    3/6
    FIG. 4
    4/6
    ΔυΕΙ (%)
    FIG. 5
    2Χ + Υ (-)
    5/6
    o »Jωω>φ! ιο>2 ! 1CL! I Ο (ΛΦ ΟΟ ο. e: j ο Τ3 Φ ί | Ç3 £! 1 D) •ç ! ί Φ CL I ω
    1 -------- 1ΟοΟΟCSIL—CB ASSo and o CÜ α. ΟS ™ 0«« 5 οοΦ £ tj 2 φ o ° - ο ç mei£ ó Φ Iffl * “o <_Φ cΌ aj 2(Π φ mean ofperatui i po ANDAND IS ra XThe; s frog2 O O l &&> c Φ Êc o Φ LO ΦÜí '1-ω£
    Final product Other treatments (galvanizing, galvannealing, electroplating, or similar)
    类似技术:
    公开号 | 公开日 | 专利标题
    BR112012018552B1|2019-01-22|high strength cold rolled steel sheet and production method thereof
    ES2759051T3|2020-05-07|Hot rolled steel sheet and manufacturing method thereof
    ES2770038T3|2020-06-30|Cold rolled steel sheet and method for its manufacture
    RU2559070C2|2015-08-10|High-strength cold-rolled steel plate with excellent uniform relative elongation and ability for hole expansion and method of its production
    US11193180B2|2021-12-07|High-strength steel sheet and method for manufacturing the same
    EP3128026B1|2019-03-06|High-strength cold rolled steel sheet exhibiting excellent material-quality uniformity, and production method therefor
    BR112015024854B1|2020-03-10|HOT LAMINATED STEEL SHEET AND METHOD FOR ITS PRODUCTION
    BR112014017100B1|2019-04-24|HOT STAMPED STEEL AND METHOD FOR HOT STAMPED PRODUCTION
    BR112017012766B1|2021-06-01|HIGH STRENGTH SEAMLESS STEEL PIPE FOR PETROLEUM INDUSTRY PIPE PRODUCTS AND THEIR PRODUCTION METHOD
    EP2762579B2|2021-03-03|High-strength hot-dip galvanized steel sheet and process for producing same
    EP3187613B1|2019-09-04|High-strength cold-rolled steel sheet and method for producing same
    MX2014011619A|2014-10-17|High-strength cold-rolled steel sheet, high-strength galvanized steel sheet and high-strength galvannealed steel sheet, having excellent formability and shape fixability, and processes for manufacturing same.
    BR112019010681A2|2019-09-17|high strength steel sheet
    BR112014017020B1|2020-04-14|cold rolled steel sheet and method for producing cold rolled steel sheet
    BR112012018697B1|2018-11-21|steel sheet and steel sheet production method
    BR112015024777B1|2020-05-12|HOT PRINTED STEEL, COLD LAMINATED STEEL SHEET AND METHOD TO PRODUCE HOT STAMPED STEEL SHEET
    BR112014001589B1|2019-01-08|high strength steel sheet and high strength galvanized steel sheet excellent in conformability and production methods thereof
    BR112017027412B1|2021-07-06|COLD LAMINATED STEEL SHEET, HOT IMMERSION GALVANIZED STEEL SHEET AND GALVANIZED STEEL SHEET
    BRPI1013802B1|2019-10-29|high strength galvanized steel sheet and method for producing it
    BR112019027154A2|2020-06-30|hot rolled steel sheet and method of manufacturing it
    BR112014025955B1|2018-12-18|high strength steel plate and method to manufacture the same
    BR112019016882A2|2020-04-14|hot stamping molded body
    WO2018055687A1|2018-03-29|Steel plate
    BR102013010172A2|2015-06-16|High strength cold rolled steel plate suitable for chemical conversion treatment and method of production
    BR112019017074A2|2020-04-07|hot stamped body
    同族专利:
    公开号 | 公开日
    JP4903915B2|2012-03-28|
    KR101447791B1|2014-10-06|
    ES2706879T3|2019-04-01|
    US20130037180A1|2013-02-14|
    CN102712980A|2012-10-03|
    CA2787575C|2015-03-31|
    CN102712980B|2014-07-02|
    CA2787575A1|2011-08-04|
    WO2011093319A1|2011-08-04|
    EP2530179B1|2018-11-14|
    PL2530179T3|2019-04-30|
    JPWO2011093319A1|2013-06-06|
    US8951366B2|2015-02-10|
    KR20120096109A|2012-08-29|
    MX2012008590A|2012-09-07|
    EP2530179A1|2012-12-05|
    BR112012018552A2|2016-05-03|
    EP2530179A4|2017-05-24|
    MX356054B|2018-05-11|
    引用文献:
    公开号 | 申请日 | 公开日 | 申请人 | 专利标题
    JPH0564215B2|1985-03-22|1993-09-14|Nippon Steel Corp|
    JP2601581B2|1991-09-03|1997-04-16|新日本製鐵株式会社|Manufacturing method of high strength composite structure cold rolled steel sheet with excellent workability|
    JP3577957B2|1998-07-29|2004-10-20|Ｊｆｅスチール株式会社|Method for producing high carbon steel sheet excellent in formability and hardenability|
    JP4059050B2|2001-10-05|2008-03-12|Ｊｆｅスチール株式会社|Cold rolled steel plate manufacturing base plate, high strength and high ductility cold rolled steel plate and methods for producing them|
    JP3875958B2|2003-03-07|2007-01-31|新日本製鐵株式会社|High strength and high ductility hot dip galvanized steel sheet with excellent workability and manufacturing method thereof|
    JP4210147B2|2003-05-06|2009-01-14|新日本製鐵株式会社|Method of hydroforming high strength steel|
    JP4619262B2|2005-10-24|2011-01-26|新日本製鐵株式会社|Press forming method of high strength steel sheet with residual austenite transformation induced plasticity|
    JP5082451B2|2006-01-24|2012-11-28|Ｊｆｅスチール株式会社|Method for producing high-strength cold-rolled steel sheet excellent in deep drawability and ductility, and method for producing high-strength hot-dip galvanized steel sheet using the cold-rolled steel sheet|
    JP4324225B1|2008-03-07|2009-09-02|株式会社神戸製鋼所|High strength cold-rolled steel sheet with excellent stretch flangeability|
    JP5126844B2|2008-08-19|2013-01-23|新日鐵住金株式会社|Steel sheet for hot pressing, manufacturing method thereof, and manufacturing method of hot pressed steel sheet member|
    JP4977185B2|2009-04-03|2012-07-18|株式会社神戸製鋼所|High-strength cold-rolled steel sheet with excellent balance between elongation and stretch flangeability and method for producing the same|
    JP4977184B2|2009-04-03|2012-07-18|株式会社神戸製鋼所|High-strength cold-rolled steel sheet with excellent balance between elongation and stretch flangeability and method for producing the same|
    JP5363867B2|2009-04-24|2013-12-11|株式会社神戸製鋼所|High strength cold-rolled steel sheet with excellent elongation and stretch flangeability|JP5462736B2|2010-07-08|2014-04-02|株式会社神戸製鋼所|Manufacturing method of high-strength steel sheet|
    JP4941619B2|2010-08-23|2012-05-30|住友金属工業株式会社|Cold rolled steel sheet and method for producing the same|
    KR101311089B1|2011-01-28|2013-09-25|현대제철 주식회사|Hot-rolled steel sheet, method of manufacturing the hot-rolled steel sheet and method of manufacturing oil tubular country goods using the hot-rolled steel sheet|
    JP5825119B2|2011-04-25|2015-12-02|Ｊｆｅスチール株式会社|High-strength steel sheet with excellent workability and material stability and method for producing the same|
    JP5397437B2|2011-08-31|2014-01-22|Ｊｆｅスチール株式会社|Hot-rolled steel sheet for cold-rolled steel sheet, hot-rolled steel sheet for hot-dip galvanized steel sheet, and manufacturing method thereof excellent in workability and material stability|
    JP5440672B2|2011-09-16|2014-03-12|Ｊｆｅスチール株式会社|High-strength steel sheet with excellent workability and method for producing the same|
    JP5365673B2|2011-09-29|2013-12-11|Ｊｆｅスチール株式会社|Hot rolled steel sheet with excellent material uniformity and method for producing the same|
    MX2014003714A|2011-09-30|2014-07-09|Nippon Steel & Sumitomo Metal Corp|High-strength hot dip galvanized steel plate having excellent moldability, weak material anisotropy and ultimate tensile strength of 980 mpa or more, high-strength alloyed hot dip galvanized steel plate and manufacturing method therefor.|
    IN2014CN04330A|2011-12-15|2015-09-04|Kobe Steel Ltd|
    KR101353551B1|2011-12-22|2014-01-23|주식회사 포스코|High carbon hot/cold rolled steel coil and manufactureing method thereof|
    EP2803744B1|2012-01-13|2018-05-02|Nippon Steel & Sumitomo Metal Corporation|Cold-rolled steel sheet and method for producing same|
    BR112014017100B1|2012-01-13|2019-04-24|Nippon Steel & Sumitomo Metal Corporation|HOT STAMPED STEEL AND METHOD FOR HOT STAMPED PRODUCTION|
    WO2013105631A1|2012-01-13|2013-07-18|新日鐵住金株式会社|Hot stamp molded article and method for producing same|
    CN104040010B|2012-01-13|2016-06-15|新日铁住金株式会社|The manufacture method of cold-rolled steel sheet and cold-rolled steel sheet|
    TWI468534B|2012-02-08|2015-01-11|Nippon Steel & Sumitomo Metal Corp|High-strength cold rolled steel sheet and manufacturing method thereof|
    KR101355796B1|2012-03-29|2014-01-28|현대제철 주식회사|Method of manufacturing steel sheet|
    KR102044693B1|2012-03-30|2019-11-14|뵈스트알파인 스탈 게엠베하|High strength cold rolled steel sheet and method of producing such steel sheet|
    KR102060534B1|2012-03-30|2019-12-30|뵈스트알파인 스탈 게엠베하|High strength cold rolled steel sheet and method of producing such steel sheet|
    KR102060522B1|2012-03-30|2019-12-30|뵈스트알파인 스탈 게엠베하|High strength cold rolled steel sheet and method of producing such steel sheet|
    JP5860343B2|2012-05-29|2016-02-16|株式会社神戸製鋼所|High strength cold-rolled steel sheet with small variations in strength and ductility and method for producing the same|
    CN104583424B|2012-06-05|2017-03-08|蒂森克虏伯钢铁欧洲股份公司|The manufacture method of steel, flat product and flat product|
    RU2600460C2|2012-06-28|2016-10-20|ДжФЕ СТИЛ КОРПОРЕЙШН|Tube from high-carbon steel with excellent processability in cold state, processability and hardenability and its manufacturing method|
    JP5860354B2|2012-07-12|2016-02-16|株式会社神戸製鋼所|High-strength hot-dip galvanized steel sheet with excellent yield strength and formability and method for producing the same|
    BR112015002312A2|2012-08-06|2017-07-04|Nippon Steel & Sumitomo Metal Corp|cold-rolled steel plate and method for producing it, and hot-formed element|
    RU2599934C2|2012-08-15|2016-10-20|Ниппон Стил Энд Сумитомо Метал Корпорейшн|Steel sheet for hot stamping, method of its manufacturing and item made from hot-stamped steel sheet|
    CN102925817B|2012-11-27|2014-10-08|莱芜钢铁集团有限公司|Cold-rolled steel sheet with yield strength of 980 MPa grade and manufacturing method thereof|
    CN103849815A|2012-11-30|2014-06-11|倪立俊|Novel building composite board|
    EP2746409A1|2012-12-21|2014-06-25|Voestalpine Stahl GmbH|Method for the heat treatment a manganese steel product and manganese steel product with a special alloy|
    KR101439696B1|2012-12-27|2014-09-12|주식회사 포스코|A high strength steel containing phosphorous|
    JP2014185359A|2013-03-22|2014-10-02|Jfe Steel Corp|High strength steel sheet|
    WO2015001367A1|2013-07-04|2015-01-08|Arcelormittal Investigación Y Desarrollo Sl|Cold rolled steel sheet, method of manufacturing and vehicle|
    WO2015011511A1|2013-07-24|2015-01-29|Arcelormittal Investigación Y Desarrollo Sl|Steel sheet having very high mechanical properties of strength and ductility, manufacturing method and use of such sheets|
    KR101912512B1|2014-01-29|2018-10-26|제이에프이 스틸 가부시키가이샤|High-strength cold-rolled steel sheet and method for manufacturing the same|
    CN105899705B|2014-03-20|2017-12-08|新日铁住金株式会社|Good processability steel wire rod and its manufacture method|
    EP3128027B1|2014-03-31|2018-09-05|JFE Steel Corporation|High-strength cold rolled steel sheet having high yield ratio, and production method therefor|
    EP3128023B1|2014-03-31|2018-12-26|JFE Steel Corporation|High-yield-ratio high-strength cold rolled steel sheet and production method therefor|
    CN104018069B|2014-06-16|2016-01-20|武汉科技大学|A kind of high-performance low-carbon is containing Mo bainitic steel and preparation method thereof|
    CN104018093B|2014-06-23|2016-01-20|武汉钢铁公司|A kind of production method of high-performance cold rolled tie|
    JP6179674B2|2014-10-30|2017-08-16|Ｊｆｅスチール株式会社|High-strength steel sheet, high-strength hot-dip galvanized steel sheet, high-strength hot-dip aluminum-plated steel sheet, high-strength electrogalvanized steel sheet, and methods for producing them|
    CN104328336B|2014-11-06|2016-04-20|东北大学|Tough steel sheet of height of a kind of submicron austenite highly malleablized and preparation method thereof|
    CN104357750A|2014-11-13|2015-02-18|舞阳钢铁有限责任公司|Large-thickness hydrogen sulfide corrosion resistant steel plate and production method thereof|
    JP6252499B2|2015-01-13|2017-12-27|Ｊｆｅスチール株式会社|Manufacturing method of hot-rolled steel strip, cold-rolled steel strip and hot-rolled steel strip|
    MX2017008944A|2015-03-10|2017-12-07|Nippon Steel & Sumitomo Metal Corp|Steel for suspension spring, and method for manufacturing same.|
    CN104928575A|2015-05-13|2015-09-23|唐山钢铁集团有限责任公司|355MPa-stage automotive cold forming galvanized hot-rolled substrate and production method thereof|
    MX2017015333A|2015-05-29|2018-03-28|Jfe Steel Corp|High-strength cold-rolled steel sheet, high-strength plated steel sheet, and method for producing same.|
    JP6108046B1|2015-06-30|2017-04-05|新日鐵住金株式会社|High-strength cold-rolled steel sheet, high-strength hot-dip galvanized steel sheet, and high-strength galvannealed steel sheet|
    WO2017010741A1|2015-07-10|2017-01-19|주식회사 포스코|Ultrahigh-strength steel sheet having excellent shape and bending characteristics and manufacturing method therefor|
    CN105132827B|2015-09-09|2017-03-29|南京工程学院|A kind of high heat-intensity forged steel material for obtaining ultra tiny compound yardstick carbide|
    WO2017125773A1|2016-01-18|2017-07-27|Arcelormittal|High strength steel sheet having excellent formability and a method of manufacturing the same|
    CN109072371B|2016-01-29|2020-08-21|杰富意钢铁株式会社|High-strength steel sheet for warm working and method for producing same|
    EP3388541B1|2016-01-29|2021-01-13|JFE Steel Corporation|High-strength steel sheet for warm working, and method for producing same|
    EP3444372B1|2016-04-14|2020-12-02|JFE Steel Corporation|High strength steel sheet and manufacturing method therefor|
    AU2017263399A1|2016-05-10|2019-01-03|United States Steel Corporation|High strength steel products and annealing processes for making the same|
    CN107385348A|2016-05-16|2017-11-24|上海梅山钢铁股份有限公司|A kind of precision stamping cold-rolled steel sheet and its manufacture method|
    CN106399836B|2016-06-21|2018-10-02|宝山钢铁股份有限公司|A kind of baking hardening type high-strength steel and its manufacturing method|
    WO2017222160A1|2016-06-21|2017-12-28|현대제철 주식회사|High-strength cold rolled steel sheet having excellent bendability, and manufacturing method therefor|
    JP6524978B2|2016-07-05|2019-06-05|Ｊｆｅスチール株式会社|High strength steel plate and method of manufacturing the same|
    US11136643B2|2016-08-10|2021-10-05|Jfe Steel Corporation|High-strength steel sheet and method for producing same|
    CN107794452A|2016-08-30|2018-03-13|宝山钢铁股份有限公司|A kind of thin strap continuous casting superelevation strength and ductility product continuously surrenders automobile steel and its manufacture method|
    JP6315044B2|2016-08-31|2018-04-25|Ｊｆｅスチール株式会社|High strength steel plate and manufacturing method thereof|
    EP3508601B1|2016-08-31|2020-03-18|JFE Steel Corporation|High-strength steel plate and production method thereof|
    RU2622187C1|2016-10-31|2017-06-13|Юлия Алексеевна Щепочкина|Structural steel|
    CN106636590B|2016-12-02|2018-04-03|燕山大学|A kind of medium carbon steel thermo-mechanical processi method of alternative modifier treatment|
    KR101938078B1|2017-07-26|2019-01-14|현대제철 주식회사|Manufacturing method for high strength galvanized steel sheet having excellent formability and high strength galvanized steel sheet thereof|
    CN111527223B|2017-12-26|2021-09-21|杰富意钢铁株式会社|High-strength cold-rolled steel sheet and method for producing same|
    TW202012649A|2018-07-18|2020-04-01|日商日本製鐵股份有限公司|Steel sheet|
    US20210340653A1|2018-12-11|2021-11-04|Nippon Steel Corporation|High-strength steel plate having excellent formability, toughness and weldability, and production method of same|
    CN110592347B|2019-09-02|2021-09-10|河钢股份有限公司承德分公司|Production method of 1200 MPa-grade complex phase steel coil plate by hot rolling on-line heat treatment|
    WO2021172298A1|2020-02-28|2021-09-02|Ｊｆｅスチール株式会社|Steel sheet, member, and methods respectively for producing said steel sheet and said member|
    WO2021172299A1|2020-02-28|2021-09-02|Ｊｆｅスチール株式会社|Steel sheet, member, and methods respectively for producing said steel sheet and said member|
    WO2021172297A1|2020-02-28|2021-09-02|Ｊｆｅスチール株式会社|Steel sheet, member, and methods respectively for producing said steel sheet and said member|
    法律状态:
    2017-08-01| B25D| Requested change of name of applicant approved|Owner name: NIPPON STEEL AND SUMITOMO METAL CORPORATION (JP) |
    2018-01-23| B06A| Patent application procedure suspended [chapter 6.1 patent gazette]|
    2018-06-05| B09A| Decision: intention to grant [chapter 9.1 patent gazette]|
    2019-01-22| B16A| Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 26/01/2011, OBSERVADAS AS CONDICOES LEGAIS. |
    2019-11-26| B25A| Requested transfer of rights approved|Owner name: NIPPON STEEL CORPORATION (JP) |
    2019-11-26| B25D| Requested change of name of applicant approved|Owner name: NIPPON STEEL CORPORATION (JP) |
    2021-11-23| B21F| Lapse acc. art. 78, item iv - on non-payment of the annual fees in time|Free format text: REFERENTE A 11A ANUIDADE. |
    优先权:
    申请号 | 申请日 | 专利标题
    JP2010014363|2010-01-26|
    JP2010-014363|2010-01-26|
    JP2010088737|2010-04-07|
    JP2010-088737|2010-04-07|
    JP2010-135351|2010-06-14|
    JP2010135351|2010-06-14|
    PCT/JP2011/051459|WO2011093319A1|2010-01-26|2011-01-26|High-strength cold-rolled steel sheet, and process for production thereof|
    [返回顶部]